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• W2970713879 abstract "A new type of doubly ordered perovskite (also reported as double double perovskite, DDPv) structure combining columnar and rock-salt orders of the cations at the $A$ and $B$ sites, respectively, was recently found at high pressure for $mathrm{Mn}Rmathrm{MnSb}{mathrm{O}}_{6}$ ($R=mathrm{La}text{--}mathrm{Sm}$). Here we report further magnetic structures of these compounds. $mathrm{M}{mathrm{n}}^{2+}$ spins align into antiparallel ferromagnetic sublattices along the $x$ axis for $mathrm{MnLaMnSb}{mathrm{O}}_{6}$, while the magnetic anisotropy of $mathrm{P}{mathrm{r}}^{3+}$ magnetic moments induces their preferential order along the $z$ direction for $mathrm{MnPrMnSb}{mathrm{O}}_{6}$. The magnetic structure of $mathrm{MnNdMnSb}{mathrm{O}}_{6}$ was reported to show a spin-reorientation transition of $mathrm{M}{mathrm{n}}^{2+}$ spins from the $z$ axis towards the $x$ axis driven by the ordering of $mathrm{N}{mathrm{d}}^{3+}$ magnetic moments. The crystal-field parameters for $mathrm{P}{mathrm{r}}^{3+}$ and $mathrm{N}{mathrm{d}}^{3+}$ at the $4ephantom{rule{0.16em}{0ex}}{C}_{2}$ site of their DDPv structure have been semiempirically estimated and used to derive their energy levels and associated wave functions. The results demonstrate that the spin-reorientation transition in $mathrm{MnNdMnSb}{mathrm{O}}_{6}$ arises as a consequence of the crystal-field-induced magnetic anisotropy of $mathrm{N}{mathrm{d}}^{3+}$." @default.
• W2970713879 created "2019-09-05" @default.
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• W2970713879 date "2018-04-11" @default.
• W2970713879 modified "2023-10-18" @default.
• W2970713879 title "Anisotropic magnetic structures of the <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mi>Mn</mml:mi><mml:mi>R</mml:mi><mml:msub><mml:mrow><mml:mi>MnSbO</mml:mi></mml:mrow><mml:mn>6</mml:mn></mml:msub></mml:math> high-pressure doubly ordered perovskites ( <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mi>R</mml:mi><mml:mspace width=4pt /><mml:mo>=</mml:mo><mml:mspace width=4pt /><mml:mi>La</mml:mi></mml:math> , Pr, and Nd)" @default.
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• W2970713879 doi "https://doi.org/10.1103/physrevb.97.134408" @default.
• W2970713879 hasPublicationYear "2018" @default.
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