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- W2970783609 endingPage "109213" @default.
- W2970783609 startingPage "109213" @default.
- W2970783609 abstract "Abstract Super-porous hydrogels were prepared, which are able of fast to ultra-fast volume response to temperature and to pH, and thus show a promise as soft actuators. The hydrogels are based on the poly(N-isopropylacrylamide) (PNIPAm)/silica nanocomposite, in which the filler strongly raises the modulus and also stabilizes the pore walls against collapse during deswelling. The well-interconnected sub-millimetre-sized porosity was generated via solvent freezing during synthesis. The gels morphology makes possible both ultra-fast deswelling and re-swelling (5.5 s for 70% in both directions, in response to T). This work focused on introducing pH-responsiveness into the gels. To this end, 1–10 mol% of sodium methacrylate (SMA) were incorporated as co-monomer. Distinct pH-responsiveness was achieved already at 1 mol% of SMA. Increase of SMA content markedly expands the temperature range of the pH-responsiveness and raises its amplitude. At the same time the increase of SMA content reduces the amplitude of the T-responsiveness, which is only moderate at 10 mol% SMA. The rate of pH-response was found to be always slower than in case of the T-response: 75 s are needed for 70% of de-swelling, and 90 min for 70% of re-swelling. The vast difference in the rates of pH- and T- response can be explained by different mechanisms of stimulus propagation (momentum transfer for T, vs. diffusion for pH) and by the mechanical effect of a contracting stiff and porous surface layer (much faster pH-deswelling than re-swelling). More generally, in case of the pH-stimulus, the mechanistic limits of its propagation in ‘simple’ porous gels become evident." @default.
- W2970783609 created "2019-09-05" @default.
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- W2970783609 date "2019-11-01" @default.
- W2970783609 modified "2023-10-16" @default.
- W2970783609 title "Porous hybrid poly(N-isopropylacrylamide) hydrogels with very fast volume response to temperature and pH" @default.
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- W2970783609 doi "https://doi.org/10.1016/j.eurpolymj.2019.109213" @default.
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