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• W2971036137 abstract "The hitherto unknown influence of 1,10-phenonthroline (1,10-phen) and its derivatives on the weak chemiluminescence (CL) of periodate-peroxide has been investigated, and a novel method for CL catalysis is described. Herein, we have deconvoluted the variation in CL intensity arising from the addition of various derivatives of 1,10-phen. Interestingly, similar derivatives of 1,10-phen show interesting differences in their reactivity toward CL. Electron-withdrawing substituents on 1,10-phen boosted the CL signals, indicating a negative charge buildup on 1,10-phen in the rate-determining step. The 1,10-phen derivatives having substitution at the C5=C6 position resulted in no CL signals due to the blockage of the reactive site. Mechanistic investigations are interpreted in terms of free radical (H2O2 reaction), followed by the oxygen atom transfer via an electrophilic attack of IO4- (IO4- reaction) on 1,10-phen resulting in dioxetane with enhanced CL emission. Additionally, the relationship between electronic structures and photophysical properties was investigated using density functional theory. Our results are expected to open up promising application of 1,10-phen as a molecular catalyst, providing a new strategy for metal-free catalytic CL enhancement reaction. We believe that this would foster in gleaning more detailed information on the nature of these reactions, thereby leading to a deeper understanding of the CL mechanism." @default.
• W2971036137 created "2019-09-05" @default.
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• W2971036137 date "2019-08-30" @default.
• W2971036137 modified "2023-10-16" @default.
• W2971036137 title "Radical-Triggered Chemiluminescence of Phenanthroline Derivatives: An Insight into Radical–Aromatic Interaction" @default.
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• W2971036137 doi "https://doi.org/10.1021/acsomega.9b01785" @default.
• W2971036137 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6751721" @default.
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• W2971036137 hasPublicationYear "2019" @default.
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