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- W2971308810 abstract "The synthesis and study of a library of cyclic (aryl)(amido)carbenes (CArAmCs), which represent a class of electrophilic NHCs that feature low calculated singlet-triplet gaps (ΔEST =19.9 kcal mol-1 ; B3LYP/def2-TZVP) and exhibit reactivity profiles expected from triplet carbenes, are described. The electrophilic properties of the CArAmCs were quantified by analyzing their respective selenium adducts, which exhibited the largest downfield 77 Se NMR chemical shifts (up to 1645 ppm) measured for any NHC derivative known to date, as well as their Ir carbonyl complexes, from which large Tolman electronic parameter (TEP) values (up to 2064 cm-1 ) were ascertained. The CArAmCs were found to engage in reactions that are typically observed with triplet carbenes, including C-H insertions, [2+1] cycloadditions with alkenes as well as alkynes, and spontaneous oxidation upon exposure to oxygen." @default.
- W2971308810 created "2019-09-05" @default.
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- W2971308810 creator A5091152132 @default.
- W2971308810 date "2019-09-24" @default.
- W2971308810 modified "2023-10-18" @default.
- W2971308810 title "Cyclic (Aryl)(Amido)Carbenes: NHCs with Triplet‐like Reactivity" @default.
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- W2971308810 cites W1910047517 @default.
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- W2971308810 cites W1971877055 @default.
- W2971308810 cites W1972954856 @default.
- W2971308810 cites W1976724728 @default.
- W2971308810 cites W1982270700 @default.
- W2971308810 cites W1991312972 @default.
- W2971308810 cites W1991588461 @default.
- W2971308810 cites W2000141877 @default.
- W2971308810 cites W2004658853 @default.
- W2971308810 cites W2005227604 @default.
- W2971308810 cites W2005264507 @default.
- W2971308810 cites W2015439558 @default.
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- W2971308810 cites W2017921868 @default.
- W2971308810 cites W2018702845 @default.
- W2971308810 cites W2025519202 @default.
- W2971308810 cites W2025639553 @default.
- W2971308810 cites W2032396389 @default.
- W2971308810 cites W2034474485 @default.
- W2971308810 cites W2036606454 @default.
- W2971308810 cites W2038092103 @default.
- W2971308810 cites W2039229231 @default.
- W2971308810 cites W2042558692 @default.
- W2971308810 cites W2043214131 @default.
- W2971308810 cites W2044673397 @default.
- W2971308810 cites W2045890874 @default.
- W2971308810 cites W2046286719 @default.
- W2971308810 cites W2047893591 @default.
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- W2971308810 cites W2104061052 @default.
- W2971308810 cites W2104707801 @default.
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- W2971308810 cites W2317793640 @default.
- W2971308810 cites W2320163706 @default.
- W2971308810 cites W2320329763 @default.
- W2971308810 cites W2320990019 @default.
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- W2971308810 cites W2461223532 @default.
- W2971308810 cites W2757473771 @default.
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- W2971308810 cites W4210663153 @default.
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- W2971308810 doi "https://doi.org/10.1002/anie.201910350" @default.
- W2971308810 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31461555" @default.
- W2971308810 hasPublicationYear "2019" @default.
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