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- W2971312230 abstract "ABSTRACT Cellulose‐based polymer brushes with variable grafting densities and low dispersity were synthesized by grafting poly( n ‐butyl acrylate) (PBA) side chains from cellulose‐derived backbones via ATRP. Esterification of commercially available cellulose acetate with 2‐bromoisobutyryl bromide (2‐BiBB) in NMP provided cellulose‐based macroinitiators averaging one initiation site per double glucose unit. ATRP macroinitiators averaging up to 6 initiation sites per repeating double glucose unit were prepared by acylation of microcrystalline cellulose (MCC) in LiCl/DMAc solvent system with 2‐BiBB. A series of linear macroinitiators with narrow MWD were obtained by fractional precipitation process. The content of initiating sites was determined by elemental analysis. (Meth)acrylate side chains were then grafted from the cellulose‐based macroinitiators. The prepared cellulose‐based polymer brushes showed tunable degradation rates dependent on grafting density of the brush, following two different degradation pathways, either cleavage of the main chain or detachment of the side chains. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57 , 2426–2435" @default.
- W2971312230 created "2019-09-05" @default.
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- W2971312230 date "2019-08-29" @default.
- W2971312230 modified "2023-10-17" @default.
- W2971312230 title "Degradable cellulose‐based polymer brushes with controlled grafting densities" @default.
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- W2971312230 doi "https://doi.org/10.1002/pola.29481" @default.
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