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- W2971346210 abstract "Two-component hydrogels were formed by the supramolecular assembly of β-cyclodextrin (β-CD) and ionic liquid-type imidazolium gemini surfactants ([C14-4-C14im]Br2) in water. The mechanism for the formation of hydrogels was studied by various methods including transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD) and rheological measurements. It can be revealed that in these hydrogels, β-CD is as the host and [C14-4-C14im]Br2 is as the guest and they can form inclusion complexes. Moreover, the properties of the hydrogels of β-CD/[C14-4-C14im]Br2 are responsive to external stimuli and can be controlled by changing the host/guest ratio or the temperature. For example, by increasing the temperature, the hydrogels change into solutions and this process is reversible and reproducible. Taken together and according to the previous study, it is suggested that the main driving forces are hydrogen bonding between β-CDs, β-CD and the imidazolium headgroup of [C14-4-C14im]²⁺, β-CD and the solvent, and the hydrophobic interaction between the hydrophobic chains of [C14-4-C14im]Br2. The properties of these hydrogels led them be useful in the field of biomedical applications such as injectable drug delivery systems." @default.
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- W2971346210 date "2016-01-01" @default.
- W2971346210 modified "2023-09-25" @default.
- W2971346210 title "Self-assembled supramolecular hydrogel induced by β-cyclodextrin and ionic liquid-type imidazolium gemini surfactant A Physicochemical and engineering aspects" @default.
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