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- W2971353222 abstract "Abstract An efficient and practical organocatalytic asymmetric cascade Michael/hemiketalization/retro‐aldol reaction of unsaturated thiazolones with α‐nitroketones by using cyclohexanediamine‐derived bifunctional squaramide as the catalyst has been developed. Under mild conditions, a broad range of chiral 4‐acyloxythiazole derivatives were obtained in high yields (up to 98% yield) with excellent enantioselectivities (up to 95% ee ). Meanwhile, a few synthetic transformations have been demonstrated. magnified image" @default.
- W2971353222 created "2019-09-05" @default.
- W2971353222 creator A5001285612 @default.
- W2971353222 creator A5079462468 @default.
- W2971353222 date "2019-09-24" @default.
- W2971353222 modified "2023-10-16" @default.
- W2971353222 title "Bifunctional Squaramide‐Catalysed Asymmetric Michael/Hemiketalization/Retro‐Aldol Reaction of Unsaturated Thiazolones with α‐Nitroketones: Synthesis of Chiral 4‐Acyloxythiazole Derivatives" @default.
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- W2971353222 doi "https://doi.org/10.1002/adsc.201900901" @default.
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