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- W2971359654 abstract "This work describes an unexploited use of DMA-material pocket to determine the glass transition temperature of blends composed by nitrocellulose and poly(Ɛ-caprolactone) in film form. A total of eight blends were prepared increasing the poly(Ɛ-caprolactone) content and changes in the mechanical properties of the blends were determined by DMA-material pocket. Storage modulus, loss modulus, and tan δ were analyzed as a function of temperature. The blends and each former polymer were also analyzed by FTIR-ATR. By the spectroscopy measurements, the intermolecular interactions between poly(Ɛ-caprolactone) and nitrocellulose in the blend is observed, been an evidence of miscibility. Tg of nitrocellulose and poly(Ɛ-caprolactone), 68 and −52 °C respectively, agree with reported values. Tg of the blends shows a single peak of tan δ between the Tg values of isolated former polymers, reinforcing the good miscibility between them. Finally, Tg of the blends exhibits a logarithmic dependence of PCL content, decreasing as poly(Ɛ-caprolactone) content increases." @default.
- W2971359654 created "2019-09-12" @default.
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- W2971359654 date "2019-12-01" @default.
- W2971359654 modified "2023-10-17" @default.
- W2971359654 title "Use of DMA-material pocket to determine the glass transition temperature of nitrocellulose blends in film form" @default.
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- W2971359654 doi "https://doi.org/10.1016/j.carbpol.2019.115288" @default.
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