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- W2971569336 abstract "Abstract Next generation high energy density lithium‐ion batteries have aroused great interests worldwide. Herein, in a high‐voltage (5 V‐class) LiNi 0.5 Mn 1.5 O 4 /MCMB (graphitic mesocarbon microbeads) battery system using 1 m lithium difluoro(oxalate)borate/sulfolane, tris(trimethylsilyl) phosphite (TMSP) additive is added to significantly improve room/high temperature cycling performances. The unchanged X‐ray diffraction patterns suggest the bulk crystal structure of cycled MCMB anode and LiNi 0.5 Mn 1.5 O 4 cathode are well preserved. Moreover, soft X‐ray absorption spectroscopy (XAS) taken from bulk sensitive fluorescence‐yield (FY) mode reveals the unchanged bulk electronic structure of cycled LiNi 0.5 Mn 1.5 O 4 cathode. Therefore, it is concluded that only interface instability contributes to capacity fading of full‐cells. However, electrode/electrolyte interface and corresponding interfacial reaction processes are always “enigmatic.” First, X‐ray photoelectron spectroscopy (XPS) and in situ differential electrochemical mass spectrometry (DEMS) are used to more accurately decipher the TMSP additive action mechanism in MCMB/electrolyte interfacial reaction processes, by identifying the interfacial solid and gas byproducts, respectively. Then, the crucial role of TMSP additive in modifying cathode/electrolyte interface is revealed by XPS and soft XAS taken from surface sensitive total electron yield (TEY) mode. This paper provides valuable perspectives for formulating novel electrolytes, and for more accurately depicting additive action mechanism in “enigmatic” electrode/electrolyte interfacial reaction processes." @default.
- W2971569336 created "2019-09-12" @default.
- W2971569336 creator A5003964217 @default.
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- W2971569336 creator A5079176132 @default.
- W2971569336 creator A5080467897 @default.
- W2971569336 date "2019-09-06" @default.
- W2971569336 modified "2023-09-30" @default.
- W2971569336 title "Deciphering the Interface of a High‐Voltage (5 V‐Class) Li‐Ion Battery Containing Additive‐Assisted Sulfolane‐Based Electrolyte" @default.
- W2971569336 cites W1939181633 @default.
- W2971569336 cites W1949231392 @default.
- W2971569336 cites W1966252053 @default.
- W2971569336 cites W1968937267 @default.
- W2971569336 cites W1973053234 @default.
- W2971569336 cites W1976190487 @default.
- W2971569336 cites W1976855213 @default.
- W2971569336 cites W1983704237 @default.
- W2971569336 cites W1989358599 @default.
- W2971569336 cites W2006318126 @default.
- W2971569336 cites W2008709582 @default.
- W2971569336 cites W2012742855 @default.
- W2971569336 cites W2013192100 @default.
- W2971569336 cites W2018640583 @default.
- W2971569336 cites W2018696078 @default.
- W2971569336 cites W2022951918 @default.
- W2971569336 cites W2030994950 @default.
- W2971569336 cites W2042275419 @default.
- W2971569336 cites W2042748513 @default.
- W2971569336 cites W2042793020 @default.
- W2971569336 cites W2043305830 @default.
- W2971569336 cites W2049589433 @default.
- W2971569336 cites W2051318669 @default.
- W2971569336 cites W2052746997 @default.
- W2971569336 cites W2067763862 @default.
- W2971569336 cites W2077686020 @default.
- W2971569336 cites W2085893991 @default.
- W2971569336 cites W2087929019 @default.
- W2971569336 cites W2094316344 @default.
- W2971569336 cites W2095804075 @default.
- W2971569336 cites W2123220217 @default.
- W2971569336 cites W2125721112 @default.
- W2971569336 cites W2138414502 @default.
- W2971569336 cites W2140481249 @default.
- W2971569336 cites W2141380560 @default.
- W2971569336 cites W2164187019 @default.
- W2971569336 cites W2169030577 @default.
- W2971569336 cites W2169211003 @default.
- W2971569336 cites W2178410511 @default.
- W2971569336 cites W2268956880 @default.
- W2971569336 cites W2326826044 @default.
- W2971569336 cites W2327249574 @default.
- W2971569336 cites W2328918638 @default.
- W2971569336 cites W2331458798 @default.
- W2971569336 cites W2336808587 @default.
- W2971569336 cites W2346843506 @default.
- W2971569336 cites W2370445807 @default.
- W2971569336 cites W2515413118 @default.
- W2971569336 cites W2551868794 @default.
- W2971569336 cites W2563857983 @default.
- W2971569336 cites W2608357483 @default.
- W2971569336 cites W2609675780 @default.
- W2971569336 cites W2618037459 @default.
- W2971569336 cites W2753293769 @default.
- W2971569336 cites W2767205086 @default.
- W2971569336 cites W2767209712 @default.
- W2971569336 cites W2767329532 @default.
- W2971569336 cites W2771597036 @default.
- W2971569336 cites W2774667258 @default.
- W2971569336 cites W2779779155 @default.
- W2971569336 cites W2782945163 @default.
- W2971569336 cites W2783387067 @default.
- W2971569336 cites W2786375019 @default.
- W2971569336 cites W2789905023 @default.
- W2971569336 cites W2794150479 @default.
- W2971569336 cites W2795938785 @default.
- W2971569336 cites W2800974936 @default.
- W2971569336 cites W2802578376 @default.
- W2971569336 cites W2803110049 @default.
- W2971569336 cites W2808052649 @default.
- W2971569336 cites W2810854392 @default.
- W2971569336 cites W2887644614 @default.
- W2971569336 cites W2898936282 @default.
- W2971569336 cites W2899044989 @default.
- W2971569336 cites W2905261921 @default.
- W2971569336 cites W2911516974 @default.
- W2971569336 cites W2913014675 @default.
- W2971569336 cites W2914503464 @default.
- W2971569336 cites W2942085664 @default.