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- W2971668667 abstract "Estrogens are a category of non-degradable organic pollutants prevalent in aquatic environments with reported health risks in human and wildlife reproduction. A biotechnological approach is proposed for utilizing fungal laccase-mediated humification reactions (L-MHRs) to remove estrogens from water. Through a reactive radical-mediated C–C, C–O–C, or C–N–C covalent coupling mechanism, multifarious complex polymeric structures are generated having limited solubilities, which significantly reduces their estrogenic activity and ecotoxicity. This review highlights the available literature associated with the self/cross-coupling mechanism of fungal L-MHRs in catalyzing the single-electron oxidation of estrogens and humic acid (HA). Advances in identifying unknown estrogen-HA cross-coupling products using high-resolution mass spectrometry combined with 13C-isotope labeling and 13C NMR may provide key research directions beneficial to aquatic ecological restoration measures." @default.
- W2971668667 created "2019-09-12" @default.
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- W2971668667 date "2019-12-01" @default.
- W2971668667 modified "2023-10-14" @default.
- W2971668667 title "Fungal laccase-mediated humification of estrogens in aquatic ecosystems" @default.
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- W2971668667 doi "https://doi.org/10.1016/j.watres.2019.115040" @default.
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