FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2971736583> ?p ?o ?g. }

• W2971736583 endingPage "842" @default.
• W2971736583 startingPage "831" @default.
• W2971736583 abstract "Systematic kinetics of melt-blended Poly(lactic acid) (PLA)/Poly(butylene succinate) (PBS) and PLA/PBS/functionalized chitosan (FCH) nanobiocomposites with dicumyl peroxide (DCP) and chemical changes thereof at degradation temperatures are evaluated using thermogravimetry (TGA) and thermogravimetry coupled to Fourier transform infrared spectroscopy (TGA–FTIR). A comprehensive kinetic model is employed on above blended samples, including (i) Flynn–Wall–Ozawa, Kissinger, Kissinger–Akahira–Sunose methods to investigate the kinetic and thermodynamic variables, and (ii) Generalized master plots to propose the thermal-induced mechanism. The thermal stability of PLA/PBS reduced with increasing FCH loading up to 3 wt%, and improved for DCP treated PLA/PBS/1FCH at maximum degradation temperature (Tmax) is noticed. The activation energy estimated from Flynn-Wall-Ozawa method are (129–139 kJmol−1), (116–152 kJmol−1), (109–146 kJmol−1), (132–169 kJmol−1) and (120–166 kJmol−1) for PLA/PBS, PLA/PBS/1FCH, PLA/PBS/3FCH, PLA/PBS/1DFCH and PLA/PBS/3DFCH respectively. The generalized master plots depicts that the PLA/PBS blend exhibited L2–F1 mechanism whereas their nanobiocomposite with or without DCP followed L2–Dn and A2–L2–Dn mechanism respectively. Coupled TGA–FTIR highlights the similar kinds of products such as lactide, acetaldehyde, esters, CO2 and CO liberated during the thermal degradation of PLA/PBS blend and their nanobiocomposites. These crosslinked/branched structures are postulated by the rheological behavior which confirmed increase in the complex viscosity (η*) and storage modulus (G′) of PLA/PBS/D/1FCH." @default.
• W2971736583 created "2019-09-12" @default.
• W2971736583 creator A5037737545 @default.
• W2971736583 creator A5051888329 @default.
• W2971736583 creator A5061663473 @default.
• W2971736583 date "2019-12-01" @default.
• W2971736583 modified "2023-10-14" @default.
• W2971736583 title "Generalized kinetics for thermal degradation and melt rheology for poly (lactic acid)/poly (butylene succinate)/functionalized chitosan based reactive nanobiocomposite" @default.
• W2971736583 cites W1156701222 @default.
• W2971736583 cites W1841503018 @default.
• W2971736583 cites W1964520264 @default.
• W2971736583 cites W1967701911 @default.
• W2971736583 cites W1973887862 @default.
• W2971736583 cites W1981964461 @default.
• W2971736583 cites W1984117546 @default.
• W2971736583 cites W1985236601 @default.
• W2971736583 cites W1986197454 @default.
• W2971736583 cites W1987125104 @default.
• W2971736583 cites W1989367982 @default.
• W2971736583 cites W1990263972 @default.
• W2971736583 cites W1995941143 @default.
• W2971736583 cites W2002235586 @default.
• W2971736583 cites W2008854263 @default.
• W2971736583 cites W2020581596 @default.
• W2971736583 cites W2028316962 @default.
• W2971736583 cites W2036679287 @default.
• W2971736583 cites W2041997186 @default.
• W2971736583 cites W2042981123 @default.
• W2971736583 cites W2043008638 @default.
• W2971736583 cites W2045767341 @default.
• W2971736583 cites W2054515048 @default.
• W2971736583 cites W2055627909 @default.
• W2971736583 cites W2060297990 @default.
• W2971736583 cites W2062722568 @default.
• W2971736583 cites W2067011199 @default.
• W2971736583 cites W2072135701 @default.
• W2971736583 cites W2078793862 @default.
• W2971736583 cites W2080400254 @default.
• W2971736583 cites W2086233418 @default.
• W2971736583 cites W2088557262 @default.
• W2971736583 cites W2089165448 @default.
• W2971736583 cites W2091460809 @default.
• W2971736583 cites W2093552905 @default.
• W2971736583 cites W2112679746 @default.
• W2971736583 cites W2126943907 @default.
• W2971736583 cites W2134556494 @default.
• W2971736583 cites W2135436984 @default.
• W2971736583 cites W2238204622 @default.
• W2971736583 cites W2261753999 @default.
• W2971736583 cites W2331082414 @default.
• W2971736583 cites W2344483072 @default.
• W2971736583 cites W2462803548 @default.
• W2971736583 cites W2519476544 @default.
• W2971736583 cites W2555243069 @default.
• W2971736583 cites W2595015798 @default.
• W2971736583 cites W2605103017 @default.
• W2971736583 cites W2617034285 @default.
• W2971736583 cites W2765949258 @default.
• W2971736583 cites W2790795202 @default.
• W2971736583 cites W2896545747 @default.
• W2971736583 cites W397537288 @default.
• W2971736583 doi "https://doi.org/10.1016/j.ijbiomac.2019.09.058" @default.
• W2971736583 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31513852" @default.
• W2971736583 hasPublicationYear "2019" @default.
• W2971736583 type Work @default.
• W2971736583 sameAs 2971736583 @default.
• W2971736583 citedByCount "15" @default.
• W2971736583 countsByYear W29717365832020 @default.
• W2971736583 countsByYear W29717365832021 @default.
• W2971736583 countsByYear W29717365832022 @default.
• W2971736583 countsByYear W29717365832023 @default.
• W2971736583 crossrefType "journal-article" @default.
• W2971736583 hasAuthorship W2971736583A5037737545 @default.
• W2971736583 hasAuthorship W2971736583A5051888329 @default.
• W2971736583 hasAuthorship W2971736583A5061663473 @default.
• W2971736583 hasConcept C121332964 @default.
• W2971736583 hasConcept C127413603 @default.
• W2971736583 hasConcept C13965031 @default.
• W2971736583 hasConcept C148898269 @default.
• W2971736583 hasConcept C159985019 @default.
• W2971736583 hasConcept C160892712 @default.
• W2971736583 hasConcept C178790620 @default.
• W2971736583 hasConcept C185592680 @default.
• W2971736583 hasConcept C188027245 @default.
• W2971736583 hasConcept C192562407 @default.
• W2971736583 hasConcept C2775920511 @default.
• W2971736583 hasConcept C2779732960 @default.
• W2971736583 hasConcept C39588626 @default.
• W2971736583 hasConcept C42360764 @default.
• W2971736583 hasConcept C521977710 @default.
• W2971736583 hasConcept C523546767 @default.
• W2971736583 hasConcept C54355233 @default.
• W2971736583 hasConcept C59061564 @default.
• W2971736583 hasConcept C60100273 @default.
• W2971736583 hasConcept C62520636 @default.
• W2971736583 hasConcept C7055690 @default.
• W2971736583 hasConcept C86803240 @default.
• W2971736583 hasConceptScore W2971736583C121332964 @default.

• next