Matches in SemOpenAlex for { <https://semopenalex.org/work/W2972024332> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2972024332 abstract "Thermodynamically favored polymer–water interactions below the lower critical solution temperature (LCST) caused swelling-induced optical anisotropy (linear retardance) of thermoresponsive hydrogels based on poly(2-(2-methoxyethoxy)ethyl methacrylate). This was exploited to study the macroscopic deswelling kinetics quantitatively by a generalized polarimetry analysis method, based on measurement of the Mueller matrix and its subsequent inverse analysis via the polar decomposition approach. The derived medium polarization parameters, namely, linear retardance (δ), diattenuation (d), and depolarization coefficient (Δ), of the hydrogels showed interesting differences between the gels prepared by conventional free radical polymerization (FRP) and reversible addition–fragmentation chain transfer polymerization (RAFT) and also between dry and swollen state. The effect of temperature, cross-linking density, and polymerization technique employed to synthesize hydrogel on deswelling kinetics was systematically studied via conventional gravimetry and corroborated further with the corresponding Mueller matrix derived quantitative polarimetry characteristics (δ, d, and Δ). The RAFT gels exhibited higher swelling ratio and swelling-induced optical anisotropy compared to FRP gels and also deswelled faster at 30 °C. On the contrary, at 45 °C, deswelling was significantly retarded for the RAFT gels due to formation of a skin layer, which was confirmed and quantified via the enhanced diattenuation and depolarization parameters." @default.
- W2972024332 created "2019-09-12" @default.
- W2972024332 creator A5017850264 @default.
- W2972024332 creator A5047391966 @default.
- W2972024332 creator A5054354024 @default.
- W2972024332 creator A5080228555 @default.
- W2972024332 date "2012-01-01" @default.
- W2972024332 modified "2023-10-02" @default.
- W2972024332 title "Swelling-Induced Optical Anisotropy of Thermoresponsive Hydrogels Based on Poly(2-(2-methoxyethoxy)ethyl methacrylate): Deswelling Kinetics Probed by Quantitative Mueller Matrix Polarimetry B" @default.
- W2972024332 hasPublicationYear "2012" @default.
- W2972024332 type Work @default.
- W2972024332 sameAs 2972024332 @default.
- W2972024332 citedByCount "0" @default.
- W2972024332 crossrefType "journal-article" @default.
- W2972024332 hasAuthorship W2972024332A5017850264 @default.
- W2972024332 hasAuthorship W2972024332A5047391966 @default.
- W2972024332 hasAuthorship W2972024332A5054354024 @default.
- W2972024332 hasAuthorship W2972024332A5080228555 @default.
- W2972024332 hasConcept C108586683 @default.
- W2972024332 hasConcept C111998727 @default.
- W2972024332 hasConcept C120665830 @default.
- W2972024332 hasConcept C121120078 @default.
- W2972024332 hasConcept C121332964 @default.
- W2972024332 hasConcept C127413603 @default.
- W2972024332 hasConcept C132050475 @default.
- W2972024332 hasConcept C148898269 @default.
- W2972024332 hasConcept C15920480 @default.
- W2972024332 hasConcept C159985019 @default.
- W2972024332 hasConcept C178790620 @default.
- W2972024332 hasConcept C185592680 @default.
- W2972024332 hasConcept C188027245 @default.
- W2972024332 hasConcept C188109995 @default.
- W2972024332 hasConcept C191486275 @default.
- W2972024332 hasConcept C192562407 @default.
- W2972024332 hasConcept C2778540859 @default.
- W2972024332 hasConcept C28493345 @default.
- W2972024332 hasConcept C36928386 @default.
- W2972024332 hasConcept C42360764 @default.
- W2972024332 hasConcept C44228677 @default.
- W2972024332 hasConcept C521977710 @default.
- W2972024332 hasConcept C62520636 @default.
- W2972024332 hasConceptScore W2972024332C108586683 @default.
- W2972024332 hasConceptScore W2972024332C111998727 @default.
- W2972024332 hasConceptScore W2972024332C120665830 @default.
- W2972024332 hasConceptScore W2972024332C121120078 @default.
- W2972024332 hasConceptScore W2972024332C121332964 @default.
- W2972024332 hasConceptScore W2972024332C127413603 @default.
- W2972024332 hasConceptScore W2972024332C132050475 @default.
- W2972024332 hasConceptScore W2972024332C148898269 @default.
- W2972024332 hasConceptScore W2972024332C15920480 @default.
- W2972024332 hasConceptScore W2972024332C159985019 @default.
- W2972024332 hasConceptScore W2972024332C178790620 @default.
- W2972024332 hasConceptScore W2972024332C185592680 @default.
- W2972024332 hasConceptScore W2972024332C188027245 @default.
- W2972024332 hasConceptScore W2972024332C188109995 @default.
- W2972024332 hasConceptScore W2972024332C191486275 @default.
- W2972024332 hasConceptScore W2972024332C192562407 @default.
- W2972024332 hasConceptScore W2972024332C2778540859 @default.
- W2972024332 hasConceptScore W2972024332C28493345 @default.
- W2972024332 hasConceptScore W2972024332C36928386 @default.
- W2972024332 hasConceptScore W2972024332C42360764 @default.
- W2972024332 hasConceptScore W2972024332C44228677 @default.
- W2972024332 hasConceptScore W2972024332C521977710 @default.
- W2972024332 hasConceptScore W2972024332C62520636 @default.
- W2972024332 hasLocation W29720243321 @default.
- W2972024332 hasOpenAccess W2972024332 @default.
- W2972024332 hasPrimaryLocation W29720243321 @default.
- W2972024332 hasRelatedWork W1977774120 @default.
- W2972024332 hasRelatedWork W2018197762 @default.
- W2972024332 hasRelatedWork W2019907848 @default.
- W2972024332 hasRelatedWork W2021086355 @default.
- W2972024332 hasRelatedWork W2040797644 @default.
- W2972024332 hasRelatedWork W2060842274 @default.
- W2972024332 hasRelatedWork W2073000545 @default.
- W2972024332 hasRelatedWork W2074793105 @default.
- W2972024332 hasRelatedWork W2084828682 @default.
- W2972024332 hasRelatedWork W2094033487 @default.
- W2972024332 hasRelatedWork W2285708683 @default.
- W2972024332 hasRelatedWork W2315816500 @default.
- W2972024332 hasRelatedWork W2333408328 @default.
- W2972024332 hasRelatedWork W2356682584 @default.
- W2972024332 hasRelatedWork W2554972956 @default.
- W2972024332 hasRelatedWork W2565602901 @default.
- W2972024332 hasRelatedWork W2597847793 @default.
- W2972024332 hasRelatedWork W2767914857 @default.
- W2972024332 hasRelatedWork W3093140135 @default.
- W2972024332 hasRelatedWork W3101255958 @default.
- W2972024332 isParatext "false" @default.
- W2972024332 isRetracted "false" @default.
- W2972024332 magId "2972024332" @default.
- W2972024332 workType "article" @default.