FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2972205826> ?p ?o ?g. }

• W2972205826 endingPage "15864" @default.
• W2972205826 startingPage "15860" @default.
• W2972205826 abstract "Electrocarboxylation of organic compounds using CO2 is a promising approach toward a sustainable low-carbon society, but it is desirable to avoid the use of conventional sacrificial anodes in terms of green chemistry. Here, we report a novel electrocarboxylation methodology operating in a simple undivided cell with a nonsacrificial anode, at which tetramethylpiperidine-1-oxyl (TEMPO)-mediated alcohol oxidation takes place. Aromatic alcohols can be oxidized with high efficiency to ketones or aldehydes at the anode in the presence of a small amount of water, and then converted to α-hydroxy acids in yields of up to 61% by coupling with CO2 at the cathode. The electrocarboxylation mechanism comprising electron and proton transfers at the cathode is discussed along with experiments using various cathode materials. Electron and proton transfers are influenced by the hydrogen adsorption energy of the cathode material, which plays an important role in the electrocarboxylation efficiency." @default.
• W2972205826 created "2019-09-12" @default.
• W2972205826 creator A5021804984 @default.
• W2972205826 creator A5031401877 @default.
• W2972205826 creator A5077238999 @default.
• W2972205826 date "2019-09-06" @default.
• W2972205826 modified "2023-10-10" @default.
• W2972205826 title "Sacrificial Anode-Free Electrosynthesis of α-Hydroxy Acids via Electrocatalytic Coupling of Carbon Dioxide to Aromatic Alcohols" @default.
• W2972205826 cites W122145733 @default.
• W2972205826 cites W1970036701 @default.
• W2972205826 cites W1970123671 @default.
• W2972205826 cites W1975932897 @default.
• W2972205826 cites W1989310901 @default.
• W2972205826 cites W1991515348 @default.
• W2972205826 cites W2019280257 @default.
• W2972205826 cites W2019692171 @default.
• W2972205826 cites W2054507307 @default.
• W2972205826 cites W2059674130 @default.
• W2972205826 cites W2060745946 @default.
• W2972205826 cites W2085228185 @default.
• W2972205826 cites W2087150042 @default.
• W2972205826 cites W2094413778 @default.
• W2972205826 cites W2118369167 @default.
• W2972205826 cites W2123894238 @default.
• W2972205826 cites W2130544815 @default.
• W2972205826 cites W2140350087 @default.
• W2972205826 cites W2156803765 @default.
• W2972205826 cites W2163984427 @default.
• W2972205826 cites W2165738701 @default.
• W2972205826 cites W2171836549 @default.
• W2972205826 cites W2407203495 @default.
• W2972205826 cites W2547882462 @default.
• W2972205826 cites W2572519108 @default.
• W2972205826 cites W2572707705 @default.
• W2972205826 cites W2761551323 @default.
• W2972205826 cites W2793967588 @default.
• W2972205826 cites W2953385355 @default.
• W2972205826 doi "https://doi.org/10.1021/acssuschemeng.9b04612" @default.
• W2972205826 hasPublicationYear "2019" @default.
• W2972205826 type Work @default.
• W2972205826 sameAs 2972205826 @default.
• W2972205826 citedByCount "32" @default.
• W2972205826 countsByYear W29722058262020 @default.
• W2972205826 countsByYear W29722058262021 @default.
• W2972205826 countsByYear W29722058262022 @default.
• W2972205826 countsByYear W29722058262023 @default.
• W2972205826 crossrefType "journal-article" @default.
• W2972205826 hasAuthorship W2972205826A5021804984 @default.
• W2972205826 hasAuthorship W2972205826A5031401877 @default.
• W2972205826 hasAuthorship W2972205826A5077238999 @default.
• W2972205826 hasBestOaLocation W29722058262 @default.
• W2972205826 hasConcept C127413603 @default.
• W2972205826 hasConcept C147789679 @default.
• W2972205826 hasConcept C17525397 @default.
• W2972205826 hasConcept C178790620 @default.
• W2972205826 hasConcept C179104552 @default.
• W2972205826 hasConcept C185592680 @default.
• W2972205826 hasConcept C193115255 @default.
• W2972205826 hasConcept C42360764 @default.
• W2972205826 hasConcept C49110097 @default.
• W2972205826 hasConcept C512968161 @default.
• W2972205826 hasConcept C52859227 @default.
• W2972205826 hasConcept C530467964 @default.
• W2972205826 hasConcept C75473681 @default.
• W2972205826 hasConcept C89395315 @default.
• W2972205826 hasConceptScore W2972205826C127413603 @default.
• W2972205826 hasConceptScore W2972205826C147789679 @default.
• W2972205826 hasConceptScore W2972205826C17525397 @default.
• W2972205826 hasConceptScore W2972205826C178790620 @default.
• W2972205826 hasConceptScore W2972205826C179104552 @default.
• W2972205826 hasConceptScore W2972205826C185592680 @default.
• W2972205826 hasConceptScore W2972205826C193115255 @default.
• W2972205826 hasConceptScore W2972205826C42360764 @default.
• W2972205826 hasConceptScore W2972205826C49110097 @default.
• W2972205826 hasConceptScore W2972205826C512968161 @default.
• W2972205826 hasConceptScore W2972205826C52859227 @default.
• W2972205826 hasConceptScore W2972205826C530467964 @default.
• W2972205826 hasConceptScore W2972205826C75473681 @default.
• W2972205826 hasConceptScore W2972205826C89395315 @default.
• W2972205826 hasFunder F4320321730 @default.
• W2972205826 hasFunder F4320322120 @default.
• W2972205826 hasFunder F4320322308 @default.
• W2972205826 hasFunder F4320335322 @default.
• W2972205826 hasIssue "19" @default.
• W2972205826 hasLocation W29722058261 @default.
• W2972205826 hasLocation W29722058262 @default.
• W2972205826 hasOpenAccess W2972205826 @default.
• W2972205826 hasPrimaryLocation W29722058261 @default.
• W2972205826 hasRelatedWork W1976929250 @default.
• W2972205826 hasRelatedWork W1983935767 @default.
• W2972205826 hasRelatedWork W2015843572 @default.
• W2972205826 hasRelatedWork W2332636940 @default.
• W2972205826 hasRelatedWork W2363790998 @default.
• W2972205826 hasRelatedWork W2387133619 @default.
• W2972205826 hasRelatedWork W2531133828 @default.
• W2972205826 hasRelatedWork W4239045289 @default.
• W2972205826 hasRelatedWork W4290852043 @default.
• W2972205826 hasRelatedWork W2514336257 @default.

• next