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- W2972251146 abstract "A new method for the synthesis of 5,9‐diaza[5]helicenes is presented using 2,3‐bis(acylamino)‐substituted ortho ‐terphenyls as precursors. Activation of the amide groups and electrophilic substitution at the ortho positions of the adjacent phenyl groups leads to the 5,9‐diaza[5]helicenes. A stepwise reaction including protection of the first amino group, amide formation at the second amino group with subsequent cyclization, followed by deprotection, amide formation and cyclization at the first amino group ensures that both electrophilic substitutions take place at sufficiently activated arenes and allows for the different substituents at the diaza[5]helicenes brought in with the amide groups. The terphenyl precursors are synthesized by two Suzuki couplings of suitably substituted building blocks. Three different 5,9‐diaza[5]helicenes with aliphatic, alkenyl and methoxycarbonylalkyl substituents were prepared; the latter would allow to attach further functionalities by ester or amide linkage." @default.
- W2972251146 created "2019-09-12" @default.
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- W2972251146 date "2019-09-26" @default.
- W2972251146 modified "2023-10-16" @default.
- W2972251146 title "Synthesis of 5,9‐Diaza[5]helicenes" @default.
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- W2972251146 doi "https://doi.org/10.1002/ejoc.201901302" @default.
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