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- W2972672867 abstract "The micellar structure of six alkyl trimethylammonium halides was studied via conductivity. It was found that the aggregation number increased with the decreasing carbon chain length. Furthermore, Br− significantly enhanced the micellar formation over Cl−. However, the aggregation number and ionization degree remain similar for both anions. The modelling results validate that the counter-anions affect micellar formation via equilibrium constants, instead of their hydration size. In particular, the association constants between surfactant (both monomer and micelle) and Br− are significantly higher than Cl−. This is consistent with the qualitative description of hydrated Br− in the literature. The experimental and modelling results confirm that micelles are formed via “ion-paring/hydration” structure, instead of the conventional “packing” concept." @default.
- W2972672867 created "2019-09-19" @default.
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- W2972672867 date "2019-09-01" @default.
- W2972672867 modified "2023-09-30" @default.
- W2972672867 title "Micellar formation of cationic surfactants" @default.
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- W2972672867 doi "https://doi.org/10.1016/j.heliyon.2019.e02425" @default.
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