Matches in SemOpenAlex for { <https://semopenalex.org/work/W2972806875> ?p ?o ?g. }
- W2972806875 endingPage "134825" @default.
- W2972806875 startingPage "134825" @default.
- W2972806875 abstract "Abstract Lithium metal is considered as an ideal anode material for lithium-ion batteries, because of its highest theoretical specific capacity, energy density, low reduction potential, and lightweight. However, its practical application is being hindered by factors such as the presence of uncontrolled interfacial reactions with liquid electrolytes, unstable solid electrolyte interphase (SEI), dendrite formation due to inhomogeneous lithium-deposition and poor cycle life. Herein, Lithium ion conducting composite film comprising of cubic garnet (Li7La2.75Ca0.25Zr1.75Nb0.25O12) (LLCZN), polyvinylidene fluoride (PVDF) and lithium perchlorate (LiClO4) salt is prepared by electrospinning. The composite film induces inorganic-rich solid electrolyte interphase which is mechanically stable to suppress the formation of lithium dendrites. The Li‖Cu@LLCZN/PVDF(84:16)LiClO4 cell exhibits negligible polarization compared to a bare copper one (Li‖Cu) performed in 1 M LiPF6 ethylene carbonate (EC) diethyl carbonate (DEC) (1:1 v/v ratio) electrolyte at a current density of 0.2 mA cm−2. Moreover, the anode free full cell configuration (Cu@LLCZN/PVDF‖NMC) demonstrates improved capacity retention of 58.66% and average coulombic efficiency of 97.6% after 30th cycles compared to Cu‖NMC cell. The as-synthesized composite film induces inorganic rich (LiF and LiCl) SEI and gives required mechanical strength to suppress the lithium dendrite formation. These features endow the Cu anode with stable interface chemistry which is essential to the realization of anode-free lithium metal batteries." @default.
- W2972806875 created "2019-09-19" @default.
- W2972806875 creator A5020941272 @default.
- W2972806875 creator A5030680997 @default.
- W2972806875 creator A5030917995 @default.
- W2972806875 creator A5031136629 @default.
- W2972806875 creator A5036099568 @default.
- W2972806875 creator A5037158605 @default.
- W2972806875 creator A5038727912 @default.
- W2972806875 creator A5042803333 @default.
- W2972806875 creator A5065128662 @default.
- W2972806875 creator A5091384827 @default.
- W2972806875 date "2019-12-01" @default.
- W2972806875 modified "2023-10-17" @default.
- W2972806875 title "Li7La2.75Ca0.25Zr1.75Nb0.25O12@LiClO4 composite film derived solid electrolyte interphase for anode-free lithium metal battery" @default.
- W2972806875 cites W1974987900 @default.
- W2972806875 cites W1990410734 @default.
- W2972806875 cites W1998307590 @default.
- W2972806875 cites W2004721328 @default.
- W2972806875 cites W2011246863 @default.
- W2972806875 cites W2013679072 @default.
- W2972806875 cites W2018356684 @default.
- W2972806875 cites W2019623594 @default.
- W2972806875 cites W2030708401 @default.
- W2972806875 cites W2040269469 @default.
- W2972806875 cites W2041035867 @default.
- W2972806875 cites W2064454797 @default.
- W2972806875 cites W2071048985 @default.
- W2972806875 cites W2110395021 @default.
- W2972806875 cites W2217159267 @default.
- W2972806875 cites W2254106349 @default.
- W2972806875 cites W2265160803 @default.
- W2972806875 cites W2281878692 @default.
- W2972806875 cites W2287078245 @default.
- W2972806875 cites W2291182905 @default.
- W2972806875 cites W2291565057 @default.
- W2972806875 cites W2323438831 @default.
- W2972806875 cites W2338750183 @default.
- W2972806875 cites W2406725458 @default.
- W2972806875 cites W2493292954 @default.
- W2972806875 cites W2515574353 @default.
- W2972806875 cites W2526329958 @default.
- W2972806875 cites W2541357201 @default.
- W2972806875 cites W2563615861 @default.
- W2972806875 cites W2570376907 @default.
- W2972806875 cites W2579567274 @default.
- W2972806875 cites W2587216081 @default.
- W2972806875 cites W2589202565 @default.
- W2972806875 cites W2595092726 @default.
- W2972806875 cites W2601142170 @default.
- W2972806875 cites W2601579677 @default.
- W2972806875 cites W2603097129 @default.
- W2972806875 cites W2605190567 @default.
- W2972806875 cites W2606338376 @default.
- W2972806875 cites W2607951315 @default.
- W2972806875 cites W2613438508 @default.
- W2972806875 cites W2613775777 @default.
- W2972806875 cites W2621695518 @default.
- W2972806875 cites W2626463974 @default.
- W2972806875 cites W2724543210 @default.
- W2972806875 cites W2741070977 @default.
- W2972806875 cites W2750722923 @default.
- W2972806875 cites W2753628067 @default.
- W2972806875 cites W2767688384 @default.
- W2972806875 cites W2769530028 @default.
- W2972806875 cites W2770103843 @default.
- W2972806875 cites W2781875515 @default.
- W2972806875 cites W2782945163 @default.
- W2972806875 cites W2789363707 @default.
- W2972806875 cites W2790714615 @default.
- W2972806875 cites W2792072903 @default.
- W2972806875 cites W2801971225 @default.
- W2972806875 cites W2802058404 @default.
- W2972806875 cites W2804514400 @default.
- W2972806875 cites W2888947507 @default.
- W2972806875 cites W2898350593 @default.
- W2972806875 cites W2900162272 @default.
- W2972806875 cites W2909277545 @default.
- W2972806875 cites W2916058073 @default.
- W2972806875 cites W2945474392 @default.
- W2972806875 doi "https://doi.org/10.1016/j.electacta.2019.134825" @default.
- W2972806875 hasPublicationYear "2019" @default.
- W2972806875 type Work @default.
- W2972806875 sameAs 2972806875 @default.
- W2972806875 citedByCount "48" @default.
- W2972806875 countsByYear W29728068752020 @default.
- W2972806875 countsByYear W29728068752021 @default.
- W2972806875 countsByYear W29728068752022 @default.
- W2972806875 countsByYear W29728068752023 @default.
- W2972806875 crossrefType "journal-article" @default.
- W2972806875 hasAuthorship W2972806875A5020941272 @default.
- W2972806875 hasAuthorship W2972806875A5030680997 @default.
- W2972806875 hasAuthorship W2972806875A5030917995 @default.
- W2972806875 hasAuthorship W2972806875A5031136629 @default.
- W2972806875 hasAuthorship W2972806875A5036099568 @default.
- W2972806875 hasAuthorship W2972806875A5037158605 @default.
- W2972806875 hasAuthorship W2972806875A5038727912 @default.
- W2972806875 hasAuthorship W2972806875A5042803333 @default.