Matches in SemOpenAlex for { <https://semopenalex.org/work/W2973109150> ?p ?o ?g. }
- W2973109150 endingPage "18133" @default.
- W2973109150 startingPage "18125" @default.
- W2973109150 abstract "A flow reactor setup for noninvasive monitoring of reactions using a compact benchtop nuclear magnetic resonance (NMR) spectrometer is presented, in which a tubular flow reactor is inserted into the bore of the NMR spectrometer and operated at stationary conditions. To monitor the composition change of the reaction mixture in the flow reactor, the entire reactor is moved to different longitudinal positions in the bore. As the flow is stationary, the composition of the reaction mixture does not change with time at a fixed reactor position. Thus, also time-consuming 2D NMR techniques can be applied to elucidate unknown products. As quantitative information is obtained directly from the NMR spectrum without calibration, the method is also appropriate for quantifying substances that are unstable as pure components. As test cases, two esterification reactions, the formation of methyl formate and the formation of methyl acetate from the pure alcohols and acids, were investigated using this technique. In addition, three 2D NMR pulse sequences (H–H–COSY, HETCOR, and HMBC) were applied in flow. The comparison of the results of the present work to literature data shows that the new method gives reliable results." @default.
- W2973109150 created "2019-09-19" @default.
- W2973109150 creator A5031050474 @default.
- W2973109150 creator A5039117244 @default.
- W2973109150 creator A5040435215 @default.
- W2973109150 creator A5054718569 @default.
- W2973109150 date "2019-09-10" @default.
- W2973109150 modified "2023-09-25" @default.
- W2973109150 title "Reaction Monitoring by Benchtop NMR Spectroscopy Using a Novel Stationary Flow Reactor Setup" @default.
- W2973109150 cites W1975559961 @default.
- W2973109150 cites W1976635758 @default.
- W2973109150 cites W1978345385 @default.
- W2973109150 cites W1986567459 @default.
- W2973109150 cites W1986944305 @default.
- W2973109150 cites W1992197622 @default.
- W2973109150 cites W2025858424 @default.
- W2973109150 cites W2034753666 @default.
- W2973109150 cites W2059831412 @default.
- W2973109150 cites W2072931072 @default.
- W2973109150 cites W2092097410 @default.
- W2973109150 cites W2094272755 @default.
- W2973109150 cites W2109179101 @default.
- W2973109150 cites W2131702043 @default.
- W2973109150 cites W2143262473 @default.
- W2973109150 cites W2153029525 @default.
- W2973109150 cites W2163312591 @default.
- W2973109150 cites W2174274895 @default.
- W2973109150 cites W2333847793 @default.
- W2973109150 cites W2472739848 @default.
- W2973109150 cites W2521859074 @default.
- W2973109150 cites W2528633920 @default.
- W2973109150 cites W2563642243 @default.
- W2973109150 cites W2588136458 @default.
- W2973109150 cites W2588335318 @default.
- W2973109150 cites W2766407641 @default.
- W2973109150 cites W2796280723 @default.
- W2973109150 cites W2886873330 @default.
- W2973109150 cites W2913301739 @default.
- W2973109150 cites W2950647895 @default.
- W2973109150 cites W2950854017 @default.
- W2973109150 doi "https://doi.org/10.1021/acs.iecr.9b03048" @default.
- W2973109150 hasPublicationYear "2019" @default.
- W2973109150 type Work @default.
- W2973109150 sameAs 2973109150 @default.
- W2973109150 citedByCount "23" @default.
- W2973109150 countsByYear W29731091502020 @default.
- W2973109150 countsByYear W29731091502021 @default.
- W2973109150 countsByYear W29731091502022 @default.
- W2973109150 countsByYear W29731091502023 @default.
- W2973109150 crossrefType "journal-article" @default.
- W2973109150 hasAuthorship W2973109150A5031050474 @default.
- W2973109150 hasAuthorship W2973109150A5039117244 @default.
- W2973109150 hasAuthorship W2973109150A5040435215 @default.
- W2973109150 hasAuthorship W2973109150A5054718569 @default.
- W2973109150 hasBestOaLocation W29731091502 @default.
- W2973109150 hasConcept C103319777 @default.
- W2973109150 hasConcept C113196181 @default.
- W2973109150 hasConcept C121332964 @default.
- W2973109150 hasConcept C161790260 @default.
- W2973109150 hasConcept C178790620 @default.
- W2973109150 hasConcept C182155053 @default.
- W2973109150 hasConcept C185592680 @default.
- W2973109150 hasConcept C2780178953 @default.
- W2973109150 hasConcept C33390570 @default.
- W2973109150 hasConcept C43617362 @default.
- W2973109150 hasConcept C46141821 @default.
- W2973109150 hasConcept C62520636 @default.
- W2973109150 hasConcept C66974803 @default.
- W2973109150 hasConceptScore W2973109150C103319777 @default.
- W2973109150 hasConceptScore W2973109150C113196181 @default.
- W2973109150 hasConceptScore W2973109150C121332964 @default.
- W2973109150 hasConceptScore W2973109150C161790260 @default.
- W2973109150 hasConceptScore W2973109150C178790620 @default.
- W2973109150 hasConceptScore W2973109150C182155053 @default.
- W2973109150 hasConceptScore W2973109150C185592680 @default.
- W2973109150 hasConceptScore W2973109150C2780178953 @default.
- W2973109150 hasConceptScore W2973109150C33390570 @default.
- W2973109150 hasConceptScore W2973109150C43617362 @default.
- W2973109150 hasConceptScore W2973109150C46141821 @default.
- W2973109150 hasConceptScore W2973109150C62520636 @default.
- W2973109150 hasConceptScore W2973109150C66974803 @default.
- W2973109150 hasFunder F4320320879 @default.
- W2973109150 hasIssue "39" @default.
- W2973109150 hasLocation W29731091501 @default.
- W2973109150 hasLocation W29731091502 @default.
- W2973109150 hasOpenAccess W2973109150 @default.
- W2973109150 hasPrimaryLocation W29731091501 @default.
- W2973109150 hasRelatedWork W1985655940 @default.
- W2973109150 hasRelatedWork W2018756100 @default.
- W2973109150 hasRelatedWork W2064239116 @default.
- W2973109150 hasRelatedWork W2089873002 @default.
- W2973109150 hasRelatedWork W2093026030 @default.
- W2973109150 hasRelatedWork W2143915553 @default.
- W2973109150 hasRelatedWork W2359497114 @default.
- W2973109150 hasRelatedWork W2589007475 @default.
- W2973109150 hasRelatedWork W4249846490 @default.
- W2973109150 hasRelatedWork W4250644184 @default.
- W2973109150 hasVolume "58" @default.