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- W2973196124 abstract "This thesis is concerned with the molecular dynamics and rheology of polymer melts inthe vicinity of a hard flat surface. One initial motivation is the desire to better understandthe phenomenon of slip between flowing molten polymer and a bounding solid wall. Alternationbetween sticking and slipping boundary conditions is suspected to be the causeof 'spurt flow', widely observed in polymer extrusion. A related aim is to investigate thenature of chain entanglements at surfaces, which also has important consequences for thematerial properties of nano-composites and thin films. In addition more general effects ofconfinement are considered.The primary method of investigation is observation, using Molecular Dynamics (MD) computersimulations of relevant systems. Single-chain models are fitted to the 'fundamental'multi-chain MD simulations, and the simplifying assumptions of this coarse-graining arethen examined." @default.
- W2973196124 created "2019-09-19" @default.
- W2973196124 creator A5010322476 @default.
- W2973196124 date "2018-09-28" @default.
- W2973196124 modified "2023-09-26" @default.
- W2973196124 title "The molecular dynamics and rheology of polymer melts near the flat surface" @default.
- W2973196124 hasPublicationYear "2018" @default.
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