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- W2973506711 abstract "Abstract Biomass-derived hierarchically porous CoFe-LDH (layered double hydroxides)/CeO2 hybrid possessing an inherent peroxidase-like activity was first fabricated employing kapok as bio-template. The CeO2 fibers not only exhibited peroxidase-like activity, but also served as a support and guided the deposition of CoFe-LDH nanosheets on their surface to form a hierarchically porous network. The resultant CoFe-LDH/CeO2 hybrid acted as a peroxidase mimic to catalyze 3,3′,5,5′- tetramethylbenzidine (TMB) with H2O2 to generate a typical blue colored product. Furthermore, CoFe-LDH/CeO2 hybrid displayed superior peroxidase-like catalytic property compared to the pristineCeO2 and CoFe-LDH, which was attributed to the presence of more effective active sites of unique hierarchical-porous architecture and the synergistic effect between CoFe-LDH and CeO2. A facile and sensitive sensing system for H2O2 and glucose determination was successfully proposed, which exhibited a sensitive response to glucose ranging from 0.05–2 mM with a detection limit of 0.015 mM based on the accelerated electron transfer between TMB and H2O2 with the assistance of CoFe-LDH/CeO2. This paper offered a feasible way or the fabrication of materials with hierarchical structure and provided a new insight into seeking novel peroxidase mimics with boosted catalytic activities." @default.
- W2973506711 created "2019-09-26" @default.
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- W2973506711 date "2020-01-01" @default.
- W2973506711 modified "2023-10-05" @default.
- W2973506711 title "Biomass-derived hierarchically porous CoFe-LDH/CeO2hybrid with peroxidase-like activity for colorimetric sensing of H2O2 and glucose" @default.
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- W2973506711 doi "https://doi.org/10.1016/j.jallcom.2019.152276" @default.
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