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- W2973661615 abstract "Recent investigations disclose that semiconductor–ionic conductor materials (SIMs) as novel functional materials deliver superior ionic conductivity. However, SIMs are not utilized as electrolyte membranes in traditional fuel cells due to mixed ion–electron conduction. To address this issue, a Schottky fuel cell using In 2 O 3 –La/Pr‐doped ceria (LCP) SIMs as the electrolyte membrane is fabricated; such devices take advantage of the superior ionic conductivity of SIMs, combined with the band energy alignment to avoid short circuiting. Through adjusting the weight ratio of In 2 O 3 and LCP, a supreme power density of 730 mW cm −2 is obtained for the Schottky fuel cell operated at 550 °C, which also exhibits decent performance at low temperatures, namely, a power maximum of 370 mW cm −2 even at 500 °C. The rectification curve verifies the existence of Schottky junction in the cell, the corresponding built‐in field prevents the electron from passing through the cell to eliminate short circuiting, and simultaneously promotes the ion across the interface between the electrolyte and anode. The results develop novel In 2 O 3 –LCP SIMs with superior conductivity and also demonstrate an efficient cell configuration based on SIMs, which proposes a potential strategy for the application of intermediate/low‐temperature solid oxide fuel cells." @default.
- W2973661615 created "2019-09-26" @default.
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- W2973661615 date "2019-10-03" @default.
- W2973661615 modified "2023-10-13" @default.
- W2973661615 title "High‐Performance Fuel Cells Based on In<sub>2</sub>O<sub>3</sub>–La/Pr‐Doped Ceria Semiconductor–Ionic Conductor Materials Electrolyte" @default.
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- W2973661615 doi "https://doi.org/10.1002/ente.201900753" @default.
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