Matches in SemOpenAlex for { <https://semopenalex.org/work/W2973756076> ?p ?o ?g. }
Showing items 1 to 64 of
64
with 100 items per page.
- W2973756076 endingPage "9" @default.
- W2973756076 startingPage "9" @default.
- W2973756076 abstract "In chemistry, breaking a mirror isn’t always a harbinger of bad luck. Using a trio of catalysts and blue light, researchers have transformed a racemic mixture of mirror-image molecules into a single enantiomer of the same compound (ChemRxiv 2019, DOI: 10.26434/chemrxiv.8206634.v1). Chemists often rely on chiral catalysts to guide a reaction so that it makes just one of its product’s enantiomers. It’s far more unusual to take a racemic mixture and use a catalyst to convert all the left-handed forms into the righty versions. Catalytic deracemization is uncommon because it is difficult. Turning a racemic mixture into a single enantiomer decreases the entropy of the system, making it a thermodynamic slog. In addition, every intermediate step of the reaction from left-handed to right-handed molecule is as likely to go backward as it is forward, a principle called microscopic reversibility. Robert R. Knowles of Princeton University and Scott J. Miller of" @default.
- W2973756076 created "2019-09-26" @default.
- W2973756076 creator A5001927643 @default.
- W2973756076 date "2019-08-12" @default.
- W2973756076 modified "2023-09-27" @default.
- W2973756076 title "Racemic mixtures converted to single enantiomers" @default.
- W2973756076 doi "https://doi.org/10.1021/cen-09732-scicon6" @default.
- W2973756076 hasPublicationYear "2019" @default.
- W2973756076 type Work @default.
- W2973756076 sameAs 2973756076 @default.
- W2973756076 citedByCount "0" @default.
- W2973756076 crossrefType "journal-article" @default.
- W2973756076 hasAuthorship W2973756076A5001927643 @default.
- W2973756076 hasConcept C121332964 @default.
- W2973756076 hasConcept C124668440 @default.
- W2973756076 hasConcept C138716334 @default.
- W2973756076 hasConcept C146686406 @default.
- W2973756076 hasConcept C161790260 @default.
- W2973756076 hasConcept C178790620 @default.
- W2973756076 hasConcept C185592680 @default.
- W2973756076 hasConcept C20621625 @default.
- W2973756076 hasConcept C3141732 @default.
- W2973756076 hasConcept C32909587 @default.
- W2973756076 hasConcept C486523 @default.
- W2973756076 hasConcept C52703039 @default.
- W2973756076 hasConcept C62520636 @default.
- W2973756076 hasConcept C71240020 @default.
- W2973756076 hasConcept C7602139 @default.
- W2973756076 hasConceptScore W2973756076C121332964 @default.
- W2973756076 hasConceptScore W2973756076C124668440 @default.
- W2973756076 hasConceptScore W2973756076C138716334 @default.
- W2973756076 hasConceptScore W2973756076C146686406 @default.
- W2973756076 hasConceptScore W2973756076C161790260 @default.
- W2973756076 hasConceptScore W2973756076C178790620 @default.
- W2973756076 hasConceptScore W2973756076C185592680 @default.
- W2973756076 hasConceptScore W2973756076C20621625 @default.
- W2973756076 hasConceptScore W2973756076C3141732 @default.
- W2973756076 hasConceptScore W2973756076C32909587 @default.
- W2973756076 hasConceptScore W2973756076C486523 @default.
- W2973756076 hasConceptScore W2973756076C52703039 @default.
- W2973756076 hasConceptScore W2973756076C62520636 @default.
- W2973756076 hasConceptScore W2973756076C71240020 @default.
- W2973756076 hasConceptScore W2973756076C7602139 @default.
- W2973756076 hasIssue "32" @default.
- W2973756076 hasLocation W29737560761 @default.
- W2973756076 hasOpenAccess W2973756076 @default.
- W2973756076 hasPrimaryLocation W29737560761 @default.
- W2973756076 hasRelatedWork W2003727193 @default.
- W2973756076 hasRelatedWork W2056451713 @default.
- W2973756076 hasRelatedWork W2077006466 @default.
- W2973756076 hasRelatedWork W2078067544 @default.
- W2973756076 hasRelatedWork W2154956352 @default.
- W2973756076 hasRelatedWork W2415967343 @default.
- W2973756076 hasRelatedWork W2505063109 @default.
- W2973756076 hasRelatedWork W2950615066 @default.
- W2973756076 hasRelatedWork W4235709924 @default.
- W2973756076 hasRelatedWork W4250644372 @default.
- W2973756076 hasVolume "97" @default.
- W2973756076 isParatext "false" @default.
- W2973756076 isRetracted "false" @default.
- W2973756076 magId "2973756076" @default.
- W2973756076 workType "article" @default.