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• W2973934750 abstract "Fourteen uranyl ion complexes have been obtained from reaction of 1,2-, 1,3-, or 1,4-phenylenediacetic acids (1,2-, 1,3-, or 1,4-H2PDA) with uranyl nitrate under solvo-hydrothermal conditions and in the presence of diverse additional metal ions and/or N-donor chelating or macrocyclic species. The complexes [UO2(1,2-PDA)(bipy)]·CH3CN (1), [UO2(1,2-PDA)(phen)] (2), [UO2(1,3-PDA)(bipy)] (3), and [UO2(1,3-PDA)(phen)] (4), where bipy = 2,2′-bipyridine and phen = 1,10-phenanthroline, crystallize as simple monoperiodic (1D) coordination polymers with slightly variable geometry and mode of association through weak interactions. Complex 5, [H2-2.2.2][(UO2)2(1,2-PDA)3]·CH3CN, containing diprotonated [2.2.2]cryptand, crystallizes as a ladder-like 1D polymer, while [NH4]6[Ni(H2O)6]2[(UO2)4(1,2-PDA)6]2[(UO2)4(1,2-PDA)5(H2O)4] (6) contains both a heavily corrugated 1D subunit and a discrete, tetranuclear anionic complex. The three complexes [Cu(bipy)2(NO3)][UO2(1,2-PDA)(NO3)] (7), [Ag(bipy)2][UO2(1,2-PDA)(NO3)] (8), and [Ag(bipy)2][UO2(1,4-PDA)(NO3)] (9) display 1D arrangements close to those in complexes 1–4 due to the presence of terminal nitrate ligands. The heterometallic complex [UO2Pb(1,3-PDA)2(phen)] (10) crystallizes as a diperiodic (2D) network built from 1D ribbons arranged in roof-tile fashion and connected to one another by Pb–O(oxo) links. [(UO2)2Pb2(1,4-PDA)3(HCOO)2(phen)2] (11) displays 1D triple-stranded (UO2)2(1,4-PDA)32– subunits assembled into a corrugated 2D polymer by double rows of Pb(HCOO)(phen)+ bridges. [Zn(bipy)3][(UO2)2(1,2-PDA)(1,4-PDA)2]·H2O (12) contains two phenylenediacetate isomers and displays zigzag chains linked to one another by dinuclear rings to give a 2D assembly containing large, elongated decanuclear rings. The two complexes [Cu(R,S-Me6cyclam)][UO2(1,3-PDA)(NO3)]2 (13) and [Ni(cyclam)][(UO2)2(1,3-PDA)3] (14), where cyclam = 1,4,8,11-tetraazacyclotetradecane and R,S-Me6cyclam = 7(R),14(S)-5,5,7,12,12,14-hexamethylcyclam, are a 1D polymer analogous to 7–9 and a 2D species containing triple-stranded subunits similar to those in 11, respectively. These and previous results show that the phenylenediacetate ligands have a strong propensity to give 1D polymers with the uranyl ion, which can only be partially overcome through the incorporation of additional metal cations, either bound to N-donors to form bulky, structure-directing counterions or as part of heterometallic polymers." @default.
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• W2973934750 date "2019-09-19" @default.
• W2973934750 modified "2023-10-18" @default.
• W2973934750 title "1,2-, 1,3-, and 1,4-Phenylenediacetate Complexes of the Uranyl Ion with Additional Metal Cations and/or Ancillary <i>N</i>-Donor Ligands: Confronting Ligand Geometrical Proclivities" @default.
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• W2973934750 doi "https://doi.org/10.1021/acs.cgd.9b01032" @default.
• W2973934750 hasPublicationYear "2019" @default.
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