FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2974098532> ?p ?o ?g. }

• W2974098532 endingPage "7243" @default.
• W2974098532 startingPage "7233" @default.
• W2974098532 abstract "The design and development of catalysts for dodecahydro-N-ethylcarbazole (12H-NECZ) dehydrogenation restrict the achievement of the cyclic hydrogenation/dehydrogenation process. In this work, the M/SiO2 (M = Pt, Pd, Ru, Rh, Au) and bimetallic PdAu/SiO2 catalysts are prepared, and their catalytic performances are measured. By XRD, XPS, HRTEM, and CO pulse chemisorption, we find that the alloy structure is not generated and the average particle size increases with the improvement of the Au amount in the bimetallic catalysts. Besides, the catalytic performance can be enhanced dramatically with introducing a small amount Au. Pd3Au1/SiO2 exhibits the best catalytic performance with the complete conversion, 94.9 selectivity to NECZ, and 5.7 wt % hydrogen release amount. The TOF values are up to 240.7 min–1, 2.26 times higher than that of Pd/SiO2. The qualitative and quantitative analyses indicate that 4H-NECZ dehydrogenation is the rate-limiting step. It can be proposed that controlling the particle size and dispersion of the PdAu/SiO2 bimetallic catalysts will bring a significant enhancement of catalytic performance." @default.
• W2974098532 created "2019-09-26" @default.
• W2974098532 creator A5051015375 @default.
• W2974098532 creator A5060828641 @default.
• W2974098532 creator A5089171218 @default.
• W2974098532 date "2019-09-16" @default.
• W2974098532 modified "2023-10-18" @default.
• W2974098532 title "Enhancing the Catalytic Activity and Selectivity of PdAu/SiO₂ Bimetallic Catalysts for Dodecahydro-<i>N</i>-ethylcarbazole Dehydrogenation by Controlling the Particle Size and Dispersion" @default.
• W2974098532 cites W1833291165 @default.
• W2974098532 cites W1946962016 @default.
• W2974098532 cites W1964076172 @default.
• W2974098532 cites W1973434078 @default.
• W2974098532 cites W1979544533 @default.
• W2974098532 cites W1985921221 @default.
• W2974098532 cites W1988488580 @default.
• W2974098532 cites W1990555735 @default.
• W2974098532 cites W1992786385 @default.
• W2974098532 cites W1998114078 @default.
• W2974098532 cites W2007395042 @default.
• W2974098532 cites W2009175552 @default.
• W2974098532 cites W2015855652 @default.
• W2974098532 cites W2025246839 @default.
• W2974098532 cites W2027054024 @default.
• W2974098532 cites W2032937782 @default.
• W2974098532 cites W2045472514 @default.
• W2974098532 cites W2049079467 @default.
• W2974098532 cites W2049553259 @default.
• W2974098532 cites W2053459719 @default.
• W2974098532 cites W2056456070 @default.
• W2974098532 cites W2058091123 @default.
• W2974098532 cites W2059862326 @default.
• W2974098532 cites W2062154396 @default.
• W2974098532 cites W2069114765 @default.
• W2974098532 cites W2079105963 @default.
• W2974098532 cites W2101730580 @default.
• W2974098532 cites W2113772969 @default.
• W2974098532 cites W2154326368 @default.
• W2974098532 cites W2276720620 @default.
• W2974098532 cites W2325910901 @default.
• W2974098532 cites W2335664455 @default.
• W2974098532 cites W2336159253 @default.
• W2974098532 cites W2406788928 @default.
• W2974098532 cites W2465716502 @default.
• W2974098532 cites W2512905351 @default.
• W2974098532 cites W2515475574 @default.
• W2974098532 cites W2534971683 @default.
• W2974098532 cites W2554868789 @default.
• W2974098532 cites W2626069083 @default.
• W2974098532 cites W2763166199 @default.
• W2974098532 cites W2765118136 @default.
• W2974098532 cites W2790273897 @default.
• W2974098532 cites W2792630044 @default.
• W2974098532 cites W2817159468 @default.
• W2974098532 cites W2902360486 @default.
• W2974098532 cites W2906363428 @default.
• W2974098532 cites W4211164327 @default.
• W2974098532 doi "https://doi.org/10.1021/acsaem.9b01202" @default.
• W2974098532 hasPublicationYear "2019" @default.
• W2974098532 type Work @default.
• W2974098532 sameAs 2974098532 @default.
• W2974098532 citedByCount "31" @default.
• W2974098532 countsByYear W29740985322020 @default.
• W2974098532 countsByYear W29740985322021 @default.
• W2974098532 countsByYear W29740985322022 @default.
• W2974098532 countsByYear W29740985322023 @default.
• W2974098532 crossrefType "journal-article" @default.
• W2974098532 hasAuthorship W2974098532A5051015375 @default.
• W2974098532 hasAuthorship W2974098532A5060828641 @default.
• W2974098532 hasAuthorship W2974098532A5089171218 @default.
• W2974098532 hasConcept C118792377 @default.
• W2974098532 hasConcept C119889771 @default.
• W2974098532 hasConcept C120665830 @default.
• W2974098532 hasConcept C121332964 @default.
• W2974098532 hasConcept C127413603 @default.
• W2974098532 hasConcept C146088050 @default.
• W2974098532 hasConcept C161368742 @default.
• W2974098532 hasConcept C161790260 @default.
• W2974098532 hasConcept C171250308 @default.
• W2974098532 hasConcept C175708663 @default.
• W2974098532 hasConcept C177562468 @default.
• W2974098532 hasConcept C178790620 @default.
• W2974098532 hasConcept C185592680 @default.
• W2974098532 hasConcept C187530423 @default.
• W2974098532 hasConcept C191897082 @default.
• W2974098532 hasConcept C192562407 @default.
• W2974098532 hasConcept C2780026712 @default.
• W2974098532 hasConcept C33790079 @default.
• W2974098532 hasConcept C42360764 @default.
• W2974098532 hasConcept C43411465 @default.
• W2974098532 hasConceptScore W2974098532C118792377 @default.
• W2974098532 hasConceptScore W2974098532C119889771 @default.
• W2974098532 hasConceptScore W2974098532C120665830 @default.
• W2974098532 hasConceptScore W2974098532C121332964 @default.
• W2974098532 hasConceptScore W2974098532C127413603 @default.
• W2974098532 hasConceptScore W2974098532C146088050 @default.
• W2974098532 hasConceptScore W2974098532C161368742 @default.
• W2974098532 hasConceptScore W2974098532C161790260 @default.
• W2974098532 hasConceptScore W2974098532C171250308 @default.

• next