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- W2974255576 abstract "An unprecedented three-component coupling involving arynes, allyl bromides, and CO2 is described, providing efficient and facile access to structurally diverse ortho-brominated aryl esters. Unlike the conventional role played in organic synthesis as electrophiles, organic bromides served as nucleophiles in this reaction, affording a new approach to multicomponent reactions (MCRs) involving aryne intermediates. Additionally, Hammett analysis suggests that two reaction mechanisms exist, depending on the electronic nature of the cinnamyl bromides used." @default.
- W2974255576 created "2019-09-26" @default.
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- W2974255576 date "2019-01-01" @default.
- W2974255576 modified "2023-10-12" @default.
- W2974255576 title "Direct bromocarboxylation of arynes using allyl bromides and carbon dioxide" @default.
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- W2974255576 doi "https://doi.org/10.1039/c9cc05495b" @default.
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