Matches in SemOpenAlex for { <https://semopenalex.org/work/W2974794577> ?p ?o ?g. }
- W2974794577 endingPage "13312" @default.
- W2974794577 startingPage "13306" @default.
- W2974794577 abstract "Efficient photochemical vapor generation (PVG) of tungsten has been achieved for the first time using a 19 W thin film flow-through photoreactor. The volatile product (most probably tungsten hexacarbonyl) was generated using a flow injection mode and 40% (v/v) formic acid as the reaction medium. An inductively coupled plasma mass spectrometer was utilized for ultrasensitive detection. The addition of Cd2+ as a sensitizer was critical, enhancing the overall PVG efficiency some 30 000-fold. At an optimal irradiation time of 19 s, a 6.1-fold enhancement factor and an overall PVG efficiency of 43% were determined from a comparison of the response to direct solution nebulization when using a sample flow rate of 2 mL min-1 and 500 mg L-1 Cd2+ as a sensitizer. A limit of detection of 0.9 ng L-1 and repeatability (RSD) of 2% at 100 ng L-1 were achieved. Interference from inorganic acids (HNO3, HCl, H2SO4, and HF) was investigated with respect to analytical application to real samples. The accuracy and practical feasibility of this ultrasensitive methodology was successfully verified by analysis of Certified Reference Material CTA-FFA-1 (Fine Fly Ash) and six natural water samples with low W concentrations." @default.
- W2974794577 created "2019-09-26" @default.
- W2974794577 creator A5006548026 @default.
- W2974794577 creator A5025795353 @default.
- W2974794577 creator A5040116630 @default.
- W2974794577 date "2019-09-20" @default.
- W2974794577 modified "2023-10-03" @default.
- W2974794577 title "Cadmium Assisted Photochemical Vapor Generation of Tungsten for Detection by Inductively Coupled Plasma Mass Spectrometry" @default.
- W2974794577 cites W1963485564 @default.
- W2974794577 cites W1979342287 @default.
- W2974794577 cites W1982272019 @default.
- W2974794577 cites W1984848168 @default.
- W2974794577 cites W1992153868 @default.
- W2974794577 cites W1992410696 @default.
- W2974794577 cites W1999862563 @default.
- W2974794577 cites W2007508756 @default.
- W2974794577 cites W2007774048 @default.
- W2974794577 cites W2008124023 @default.
- W2974794577 cites W2043588812 @default.
- W2974794577 cites W2046223112 @default.
- W2974794577 cites W2060398962 @default.
- W2974794577 cites W2067998089 @default.
- W2974794577 cites W2073779727 @default.
- W2974794577 cites W2077699115 @default.
- W2974794577 cites W2081628446 @default.
- W2974794577 cites W2082168607 @default.
- W2974794577 cites W2082206535 @default.
- W2974794577 cites W2087571162 @default.
- W2974794577 cites W2090714744 @default.
- W2974794577 cites W2095698156 @default.
- W2974794577 cites W2144613388 @default.
- W2974794577 cites W2159123497 @default.
- W2974794577 cites W2196048673 @default.
- W2974794577 cites W2222574492 @default.
- W2974794577 cites W2317194791 @default.
- W2974794577 cites W2319774448 @default.
- W2974794577 cites W2320329323 @default.
- W2974794577 cites W2330178499 @default.
- W2974794577 cites W2419145425 @default.
- W2974794577 cites W2528774069 @default.
- W2974794577 cites W2613254854 @default.
- W2974794577 cites W2763359428 @default.
- W2974794577 cites W2779430160 @default.
- W2974794577 cites W2792339195 @default.
- W2974794577 cites W2795576041 @default.
- W2974794577 cites W2802222757 @default.
- W2974794577 cites W2802544459 @default.
- W2974794577 cites W2804092224 @default.
- W2974794577 cites W2886536568 @default.
- W2974794577 cites W2891645619 @default.
- W2974794577 cites W2895962266 @default.
- W2974794577 cites W2904612675 @default.
- W2974794577 cites W2908753829 @default.
- W2974794577 cites W2921395178 @default.
- W2974794577 cites W2926607042 @default.
- W2974794577 cites W2940131179 @default.
- W2974794577 cites W2943643739 @default.
- W2974794577 cites W2946989883 @default.
- W2974794577 doi "https://doi.org/10.1021/acs.analchem.9b04241" @default.
- W2974794577 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31537056" @default.
- W2974794577 hasPublicationYear "2019" @default.
- W2974794577 type Work @default.
- W2974794577 sameAs 2974794577 @default.
- W2974794577 citedByCount "42" @default.
- W2974794577 countsByYear W29747945772020 @default.
- W2974794577 countsByYear W29747945772021 @default.
- W2974794577 countsByYear W29747945772022 @default.
- W2974794577 countsByYear W29747945772023 @default.
- W2974794577 crossrefType "journal-article" @default.
- W2974794577 hasAuthorship W2974794577A5006548026 @default.
- W2974794577 hasAuthorship W2974794577A5025795353 @default.
- W2974794577 hasAuthorship W2974794577A5040116630 @default.
- W2974794577 hasConcept C100859065 @default.
- W2974794577 hasConcept C113196181 @default.
- W2974794577 hasConcept C119128265 @default.
- W2974794577 hasConcept C121332964 @default.
- W2974794577 hasConcept C154020017 @default.
- W2974794577 hasConcept C162356407 @default.
- W2974794577 hasConcept C165697059 @default.
- W2974794577 hasConcept C172120300 @default.
- W2974794577 hasConcept C178790620 @default.
- W2974794577 hasConcept C185592680 @default.
- W2974794577 hasConcept C2777379063 @default.
- W2974794577 hasConcept C43617362 @default.
- W2974794577 hasConcept C542268612 @default.
- W2974794577 hasConcept C62520636 @default.
- W2974794577 hasConcept C82706917 @default.
- W2974794577 hasConcept C95974651 @default.
- W2974794577 hasConceptScore W2974794577C100859065 @default.
- W2974794577 hasConceptScore W2974794577C113196181 @default.
- W2974794577 hasConceptScore W2974794577C119128265 @default.
- W2974794577 hasConceptScore W2974794577C121332964 @default.
- W2974794577 hasConceptScore W2974794577C154020017 @default.
- W2974794577 hasConceptScore W2974794577C162356407 @default.
- W2974794577 hasConceptScore W2974794577C165697059 @default.
- W2974794577 hasConceptScore W2974794577C172120300 @default.
- W2974794577 hasConceptScore W2974794577C178790620 @default.
- W2974794577 hasConceptScore W2974794577C185592680 @default.