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- W2975081118 endingPage "104136" @default.
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- W2975081118 abstract "Abstract Red phosphorus (red-P) has been studied intensively due to its high theoretical capacity. However, it remains a challenge to achieve outstanding rate performance because of a large ion radius of Na+ and insulation of red-P. Herein, BaTiO3 (BTO) is used as functional additive to promote Na+ diffusion based on piezoelectric effect induced by volume expansion of red-P. Micro red-Phosphorus/BaTiO3/Graphene (red-P/BTO/G) composite is prepared via a ball-milling method. After 100 cycles, the discharge capacity remains 823 mAh·g−1. The good performance of micro red-P/BTO/G composite is attributed to the enhanced diffusion kinetics brought by BTO, which makes the speed 110 times faster than red-P/G composite. Moreover, an increased diffusion rate has been acquired through polarization of BTO in high voltage electric field to get aligned polarization direction, with the speed 1.8 times of unpolarized red-P/BTO/G material. The mechanism how BTO promotes Na+ diffusion in discharge process is explained in detail." @default.
- W2975081118 created "2019-10-03" @default.
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- W2975081118 date "2019-12-01" @default.
- W2975081118 modified "2023-10-17" @default.
- W2975081118 title "Boosting Na-ion diffusion by piezoelectric effect induced by alloying reaction of micro red-phosphorus/BaTiO3/graphene composite anode" @default.
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- W2975081118 doi "https://doi.org/10.1016/j.nanoen.2019.104136" @default.
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