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• W2975534040 startingPage "7717" @default.
• W2975534040 abstract "Using (S)-prolinol as a chiral auxiliary, axially chiral vinylallenes with excellent enantiopurity (up to >99% enantiomeric excess (ee)) were readily prepared from optically pure propargylamines in the presence of AgNO3 under microwave irradiation. Subsequent (hetero)-Diels–Alder reaction of these axially chiral vinylallenes with azodicarboxylates or maleimides on water demonstrates excellent axial-to-point chirality transfer (up to 99% ee)." @default.
• W2975534040 created "2019-10-03" @default.
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• W2975534040 date "2019-09-25" @default.
• W2975534040 modified "2023-10-17" @default.
• W2975534040 title "Highly Enantioselective Synthesis Using Prolinol as a Chiral Auxiliary: Silver-Mediated Synthesis of Axially Chiral Vinylallenes and Subsequent (Hetero)-Diels–Alder Reactions" @default.
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• W2975534040 doi "https://doi.org/10.1021/acs.orglett.9b02514" @default.
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