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- W2975627770 abstract "Abstract Tetraethylammonium α-dithionaphthoate (Et4N)(α-C10H7CS2) and tetraethylammonium β-dithionaphthoate (Et4N)(β-C10H7CS2) were synthesized by sequential Grignard reaction and CS2 insertion reaction from α- or β-bromo-naphthalene. Treatment of the chloro-bridged ruthenium(II) starting materials [Ru(CO)2Cl2]n, [Ru(COD)Cl2]n (COD = 1,5-cyclooctadiene) or [(η6-p-cymene)RuCl2]2 with (Et4N)(α-C10H7CS2) in refluxing tetrahydrofuran afforded the corresponding organoruthenium(II) complexes [Ru(CO)2(α-C10H7CS2)2] (1), [Ru(COD)(α-C10H7CS2)2] (2) and [(η6-p-cymene)RuCl(α-C10H7CS2)] (3), respectively. Similarly, reactions of [RuHCl(CO)(PPh3)3] or [Ru(bpy)2Cl2·2H2O] (bpy = 2,2′-bipyridine) with (Et4N)(α-C10H7CS2) gave a neutral complex [RuH(CO)(PPh3)2(α-C10H7CS2)] (4) and a cationic complex [Ru(bpy)2(α-C10H7CS2)]Cl (5), respectively. Moreover, treatment of [Ru(COD)Cl2]n with (Et4N)(β-C10H7CS2) led to isolation of an organoruthenium(II) complex [Ru(COD)(β-C10H7CS2)2] (6). Complexes 1–6 were well characterized by infrared, electronic absorption, proton nuclear magnetic resonance spectroscopies along with microanalyses, and their molecular structures were established by single-crystal X-ray diffraction. The electrochemical properties of complexes 1–6 were also investigated." @default.
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- W2975627770 date "2019-12-01" @default.
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- W2975627770 title "Ruthenium(II) complexes with α- or β-dithionaphthoato ligands" @default.
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- W2975627770 doi "https://doi.org/10.1016/j.ica.2019.119173" @default.
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