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- W2976170413 endingPage "1943" @default.
- W2976170413 startingPage "1939" @default.
- W2976170413 abstract "This paper deals with the preparation of two series of chito-oligosaccharide derivatives, chitobiose octaalkanoates, and chitotriose undecaalkanoates, in which the amino- and hydroxyl groups were blocked with alkyl pendants of differing lengths via an ester linkage. By differential scanning calorimetry(DSC) and optical microscopic observations, these compounds were found to exhibit an enantiotropic mesophase at temperatures ranging from ca. 50 °C to ca. 200 °C. The texture of the mesophases were similar to those of the discotic columnar liquid crystals formed by the cellobiose and cellotriose equivalents. However, the amido group in the chito-derivatives seems to stabilize the mesophase to an appreciable extent, bringing about higher temperatures and a longer temperature span of the mesophase than those of the cello-equivalents." @default.
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- W2976170413 date "1992-07-01" @default.
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- W2976170413 title "Thermotropic Liquid Crystals Based on Chito-Oligosaccharides. 1. Synthesis of Chitobiose Octaalkanoates and Chitotriose Undecaalkanoates and Their Thermal Properties" @default.
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- W2976170413 doi "https://doi.org/10.1246/bcsj.65.1939" @default.
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