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- W2976254696 abstract "Recent progress in the design of metal-free Lewis pair catalysts indicates a bright future for the synthesis of various polyesters with broad applications. In the present review, we attempt to highlight the recent advancements and opportunities in the use of metal-free cooperative catalysts or initiators for polymerization reactions. The ring-opening alternating copolymerization (ROAP) of epoxides with cyclic anhydrides is a typical typical polymerization reaction used here to illustrate some of the features of metal-free cooperative catalysts. In addition to the simple simplicity in the structural features of the catalysts and the desirable metal-free polyesters/polycarbonate products, these metal-free catalysts also exhibit impressive catalytic efficiency, molar mass control, and stereo-/regioselectivity. We believe that metal-free cooperative catalysis will continue to drive innovation into polymer chemistry research in the near future." @default.
- W2976254696 created "2019-10-03" @default.
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- W2976254696 date "2019-12-01" @default.
- W2976254696 modified "2023-10-18" @default.
- W2976254696 title "Progress in metal-free cooperative catalysis for the ring-opening copolymerization of cyclic anhydrides and epoxides" @default.
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- W2976254696 doi "https://doi.org/10.1016/j.eurpolymj.2019.109276" @default.
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