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• W2976275370 startingPage "8116" @default.
• W2976275370 abstract "The trifluoromethylthionyl group (−SCF3) is an efficient weak directing group for Ir(III)-catalyzed aryl C–H olefination. Various trifluoromethylthioethers provide high levels of mono-olefination products in good to excellent yields under mild conditions with a 2,2′-bipyridine ligand or AgBF4 as an additive. Mechanistic studies indicate the C–H cleavage is the rate-determining step. The directing group ability of the −SCF3 group is benchmarked against several other weak directing groups by competition experiments under Ir(III)-catalyzed conditions." @default.
• W2976275370 created "2019-10-03" @default.
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• W2976275370 date "2019-09-23" @default.
• W2976275370 modified "2023-10-14" @default.
• W2976275370 title "Ir(III)-Catalyzed Mono-Olefination of Aryl C–H Bonds Using −SCF₃ as a Weak Directing Group" @default.
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• W2976275370 doi "https://doi.org/10.1021/acs.orglett.9b03125" @default.
• W2976275370 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31545610" @default.
• W2976275370 hasPublicationYear "2019" @default.
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