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• W2976326704 startingPage "119170" @default.
• W2976326704 abstract "A novel tridecanuclear nanoscopic cluster {ZnGd12} have been synthesized by using the Schiff-base ligand, 2-methoxy-6-[(2-methylindole-2-carboxyl-1-ylidene) methyl]phenol (H2L), with zinc chloride and gadolinium nitrate in the presence of triethylamine as deprotonation reagent. Single-crystal X-ray diffraction analysis revealed that the central core of the cluster {ZnGd12} is unprecedented and composed of a beautiful structure built by two monocapped triangular prisms [ZnGd6] sharing the ZnII vertex. Magnetic studies reveal that {ZnGd12} shows promise as a low-temperature magnetic refrigerant with the magnetic field entropy of 30.79 J kg−1 K−1 at a magnetic field of 7 T–2 T." @default.
• W2976326704 created "2019-10-03" @default.
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• W2976326704 date "2020-01-01" @default.
• W2976326704 modified "2023-09-26" @default.
• W2976326704 title "A tridecanuclear {ZnGd12} nanoscopic cluster exhibiting large magnetocaloric effect" @default.
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• W2976326704 doi "https://doi.org/10.1016/j.ica.2019.119170" @default.
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