Matches in SemOpenAlex for { <https://semopenalex.org/work/W2976502013> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W2976502013 endingPage "10693" @default.
- W2976502013 startingPage "10688" @default.
- W2976502013 abstract "Abstract A novel cost effective tuneable Lewis acid/sulfur scavenging system, comprising of various ratios of group 13 stronger Lewis acid AlCl 3 and transition metal weak Lewis acid FeCl 3 , were developed for oligomerization of alpha olefins to form polyalphaolefins (PAOs). The residence time and temperature dependent oligomer ratio of 1‐decene is studied in the presence of Lewis acid catalysts containing various ratios of AlCl 3 /FeCl 3 [AlCl 3 , AlCl 3 /FeCl 3 (0.7:0.3), AlCl 3 /FeCl 3 (0.5:0.5), AlCl 3 /FeCl 3 (0.3:0.7), FeCl 3 ]. The transition metal based weak Lewis acid FeCl 3 yielded oligomer ratio comparable to commercial PAO 2 cst to PAO 6 cst viscosity grade. With an increase in AlCl 3 concentration in the catalyst system, the equilibrium oligomer ratio is shifted towards higher oligomers. With increase in temperature, due to faster termination kinetics in comparison with the propagation, the oligomer ratio is shifted towards lighter dimer and trimer oligomers. The sulfur scavenging abilities of AlCl 3 /FeCl 3 is studied in the presence of model mixture containing thiol in decene. The catalyst system showed superior sulfur scavenging abilities." @default.
- W2976502013 created "2019-10-03" @default.
- W2976502013 creator A5022073861 @default.
- W2976502013 creator A5058966571 @default.
- W2976502013 creator A5072184244 @default.
- W2976502013 creator A5088967956 @default.
- W2976502013 date "2019-09-24" @default.
- W2976502013 modified "2023-09-27" @default.
- W2976502013 title "A Dual Functional Tuneable‐Lewis Acid/Sulfur Scavenging Catalyst System for Alpha Olefin Oligomerization" @default.
- W2976502013 cites W1593603762 @default.
- W2976502013 cites W1917434550 @default.
- W2976502013 cites W1984510392 @default.
- W2976502013 cites W2005146559 @default.
- W2976502013 cites W2028276064 @default.
- W2976502013 cites W2050794873 @default.
- W2976502013 cites W2091362952 @default.
- W2976502013 cites W2130611467 @default.
- W2976502013 cites W2162447862 @default.
- W2976502013 cites W2444352686 @default.
- W2976502013 cites W4301025388 @default.
- W2976502013 doi "https://doi.org/10.1002/slct.201902008" @default.
- W2976502013 hasPublicationYear "2019" @default.
- W2976502013 type Work @default.
- W2976502013 sameAs 2976502013 @default.
- W2976502013 citedByCount "2" @default.
- W2976502013 countsByYear W29765020132019 @default.
- W2976502013 countsByYear W29765020132021 @default.
- W2976502013 crossrefType "journal-article" @default.
- W2976502013 hasAuthorship W2976502013A5022073861 @default.
- W2976502013 hasAuthorship W2976502013A5058966571 @default.
- W2976502013 hasAuthorship W2976502013A5072184244 @default.
- W2976502013 hasAuthorship W2976502013A5088967956 @default.
- W2976502013 hasConcept C161790260 @default.
- W2976502013 hasConcept C163638829 @default.
- W2976502013 hasConcept C178790620 @default.
- W2976502013 hasConcept C185592680 @default.
- W2976502013 hasConcept C188027245 @default.
- W2976502013 hasConcept C2776403692 @default.
- W2976502013 hasConcept C2779546866 @default.
- W2976502013 hasConcept C2780642029 @default.
- W2976502013 hasConcept C518881349 @default.
- W2976502013 hasConceptScore W2976502013C161790260 @default.
- W2976502013 hasConceptScore W2976502013C163638829 @default.
- W2976502013 hasConceptScore W2976502013C178790620 @default.
- W2976502013 hasConceptScore W2976502013C185592680 @default.
- W2976502013 hasConceptScore W2976502013C188027245 @default.
- W2976502013 hasConceptScore W2976502013C2776403692 @default.
- W2976502013 hasConceptScore W2976502013C2779546866 @default.
- W2976502013 hasConceptScore W2976502013C2780642029 @default.
- W2976502013 hasConceptScore W2976502013C518881349 @default.
- W2976502013 hasIssue "36" @default.
- W2976502013 hasLocation W29765020131 @default.
- W2976502013 hasOpenAccess W2976502013 @default.
- W2976502013 hasPrimaryLocation W29765020131 @default.
- W2976502013 hasRelatedWork W1490019140 @default.
- W2976502013 hasRelatedWork W1972553524 @default.
- W2976502013 hasRelatedWork W1998377570 @default.
- W2976502013 hasRelatedWork W2007464831 @default.
- W2976502013 hasRelatedWork W2086889963 @default.
- W2976502013 hasRelatedWork W3162561016 @default.
- W2976502013 hasRelatedWork W4213091046 @default.
- W2976502013 hasRelatedWork W4241914065 @default.
- W2976502013 hasRelatedWork W4244209192 @default.
- W2976502013 hasRelatedWork W4247888300 @default.
- W2976502013 hasVolume "4" @default.
- W2976502013 isParatext "false" @default.
- W2976502013 isRetracted "false" @default.
- W2976502013 magId "2976502013" @default.
- W2976502013 workType "article" @default.