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• W2976572024 abstract "A selection of benzyl-based protecting groups for thiouracil (SU) for the synthesis of pseudo-complementary peptide nucleic acid (PNA) has been evaluated. The 4-methoxybenzyl-protecting group that has found use for SU during Boc-based oligomerization is also suitable for Fmoc-based oligomerization. Furthermore, it is demonstrated that SU protection is unnecessary for the successful synthesis of thiouracil-containing PNA. The new 2-thiothymine (ST) PNA monomer has also been prepared and incorporated into an oligomer and its binding to complementary PNA evaluated." @default.
• W2976572024 created "2019-10-03" @default.
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• W2976572024 date "2019-09-24" @default.
• W2976572024 modified "2023-10-17" @default.
• W2976572024 title "On the Necessity of Nucleobase Protection for 2-Thiouracil for Fmoc-Based Pseudo-Complementary Peptide Nucleic Acid Oligomer Synthesis" @default.
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• W2976572024 doi "https://doi.org/10.1021/acs.joc.9b00821" @default.
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