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• W2976611842 endingPage "16031" @default.
• W2976611842 startingPage "16022" @default.
• W2976611842 abstract "Abstract It has been established that a cyclopentadienyl (Cp) Rh III complex with two aryl groups and a pendant amide moiety catalyzes the formal Lossen rearrangement/alkenylation cascade of N ‐pivaloyl heterole carboxamides with internal alkynes, leading to alkenylheteroles. Interestingly, the use of sterically demanding internal alkynes afforded not the alkenylation but the [3+2] annulation products ([5,5]‐fused heteroles). In these reactions, the pendant amide moiety of the CpRh III complex may accelerate the formal Lossen rearrangement. The use of five‐membered heteroles may deter reductive elimination to form strained [5,5]‐fused heteroles; instead, protonation proceeds to give the alkenylation products. Bulky alkyne substituents accelerate the reductive elimination to allow the formation of the [5,5]‐fused heteroles." @default.
• W2976611842 created "2019-10-03" @default.
• W2976611842 creator A5013437976 @default.
• W2976611842 creator A5013619496 @default.
• W2976611842 creator A5090533930 @default.
• W2976611842 date "2019-11-18" @default.
• W2976611842 modified "2023-10-18" @default.
• W2976611842 title "Formal Lossen Rearrangement/Alkenylation or Annulation Cascade of Heterole Carboxamides with Alkynes Catalyzed by CpRh^III Complexes with Pendant Amides" @default.
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