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- W297677904 abstract "The conformations of polymer chains are altered during deformation or flow of a material. These conformational changes are accompanied by changes in physical properties that are important to the development of a full understanding of polymer processing operations. In this investigation, a program is proposed to examine the fundamental relationship between chain conformational changes and resultant macroscopic material responses during deformation. The program is based on the coupling of rheological and rheo-optical measurements during well characterized deformation in order to follow the details of molecular orientation and conformational changes. An in situ infrared dichroism technique is described by which molecular orientation may be characterized dynamically during cabin deformation and relaxation. The use of novel specimens that are partially deuterium labelled allows characterization of the deformation and relaxation behavior of essentially any segment of a polymer chain. This information is of sufficient detail to test the validity of current theoretical concepts governing polymer chain orientation behavior. The success of these experiments is an important step towards a fundamental molecular description of polymer rheology." @default.
- W297677904 created "2016-06-24" @default.
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- W297677904 date "1985-05-01" @default.
- W297677904 modified "2023-09-27" @default.
- W297677904 title "Polymer chain segment orientation during stress relaxation. Annual progress report, July 1, 1984-June 30, 1985" @default.
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