Matches in SemOpenAlex for { <https://semopenalex.org/work/W2976906584> ?p ?o ?g. }
- W2976906584 endingPage "16269" @default.
- W2976906584 startingPage "16257" @default.
- W2976906584 abstract "During the processes associated with glass corrosion, porous hydrated glass alteration layers typically form upon exposure to aqueous conditions for extended time periods. The impacts of the alteration layer on glass durability have not been agreed upon in the glass science community. In particular, the formation mechanisms of hydrated glass alteration layers are still largely unknown and require further investigation, but these layers often require months to years to develop and are often too thin to adequately characterize. Meanwhile, sol-gel-derived silicate gels are relatively easy to synthesize in bulk with custom compositions relevant to hydrated glass alteration layers. If alteration layers and synthetic silicate gels demonstrate physical and chemical properties that are sufficiently similar, synthetic silicate gels could be used as analogues for hydrated glass alteration layers in future studies. However, synthetic gels must first be prepared and evaluated before comparisons between glass alteration layers and synthetic silicate gels can be made. This work focuses entirely on the synthesis and observed physical properties of synthetic silicate gels. A future work will compare the characteristics of synthetic gels described in this work with altered waste glass formed in similar pH environments. In this study, synthetic gels were made with custom compositions at various pH values to evaluate the effect of pH on gel structure and morphology. Several other variables were examined also, such as composition, drying, and aging. Gels were produced by sequential additions of organometallic precursors in a single container. Gels were analyzed with several techniques including small-angle X-ray scattering, gas adsorption, and He pycnometry to determine the effects of the variables on physical properties. Results show that gels prepared at pH 3 consistently contained fewer primary particles with diameters larger than 7.2 nm and fewer pores with diameters larger than 30 nm compared to gels synthesized at pH 7 and 9. Composition was shown to have no discernable effect on primary particle and pore sizes at any pH." @default.
- W2976906584 created "2019-10-03" @default.
- W2976906584 creator A5001723045 @default.
- W2976906584 creator A5010215345 @default.
- W2976906584 creator A5040649143 @default.
- W2976906584 date "2019-09-26" @default.
- W2976906584 modified "2023-10-16" @default.
- W2976906584 title "Sol–Gel Synthesis and Characterization of Gels with Compositions Relevant to Hydrated Glass Alteration Layers" @default.
- W2976906584 cites W1963905574 @default.
- W2976906584 cites W1964647536 @default.
- W2976906584 cites W1965510347 @default.
- W2976906584 cites W1966257485 @default.
- W2976906584 cites W1975834815 @default.
- W2976906584 cites W1980310511 @default.
- W2976906584 cites W1983956337 @default.
- W2976906584 cites W1985697490 @default.
- W2976906584 cites W1986970616 @default.
- W2976906584 cites W1987815592 @default.
- W2976906584 cites W1988067170 @default.
- W2976906584 cites W1989275496 @default.
- W2976906584 cites W1992683064 @default.
- W2976906584 cites W1994427276 @default.
- W2976906584 cites W1995756754 @default.
- W2976906584 cites W1997393979 @default.
- W2976906584 cites W1998626321 @default.
- W2976906584 cites W1998824703 @default.
- W2976906584 cites W2003667498 @default.
- W2976906584 cites W2007176087 @default.
- W2976906584 cites W2016390283 @default.
- W2976906584 cites W2019958578 @default.
- W2976906584 cites W2026580741 @default.
- W2976906584 cites W2029863085 @default.
- W2976906584 cites W2030592562 @default.
- W2976906584 cites W2031356887 @default.
- W2976906584 cites W2031827288 @default.
- W2976906584 cites W2034969239 @default.
- W2976906584 cites W2035417725 @default.
- W2976906584 cites W2036181858 @default.
- W2976906584 cites W2038989974 @default.
- W2976906584 cites W2042361161 @default.
- W2976906584 cites W2042978567 @default.
- W2976906584 cites W2049027197 @default.
- W2976906584 cites W2065188346 @default.
- W2976906584 cites W2065535790 @default.
- W2976906584 cites W2066281513 @default.
- W2976906584 cites W2070142754 @default.
- W2976906584 cites W2070695667 @default.
- W2976906584 cites W2077520447 @default.
- W2976906584 cites W2079760931 @default.
- W2976906584 cites W2081578290 @default.
- W2976906584 cites W2082993970 @default.
- W2976906584 cites W2084698737 @default.
- W2976906584 cites W2093171861 @default.
- W2976906584 cites W2094048343 @default.
- W2976906584 cites W2134319434 @default.
- W2976906584 cites W2134644154 @default.
- W2976906584 cites W2138504228 @default.
- W2976906584 cites W2140551148 @default.
- W2976906584 cites W2141947775 @default.
- W2976906584 cites W2161667268 @default.
- W2976906584 cites W2173049965 @default.
- W2976906584 cites W2321876220 @default.
- W2976906584 cites W2323171580 @default.
- W2976906584 cites W2331599080 @default.
- W2976906584 cites W2754173701 @default.
- W2976906584 cites W2766617528 @default.
- W2976906584 cites W2805347923 @default.
- W2976906584 cites W2889319766 @default.
- W2976906584 cites W2917722641 @default.
- W2976906584 cites W4233243396 @default.
- W2976906584 cites W92192243 @default.
- W2976906584 doi "https://doi.org/10.1021/acsomega.9b00491" @default.
- W2976906584 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6787893" @default.
- W2976906584 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31616803" @default.
- W2976906584 hasPublicationYear "2019" @default.
- W2976906584 type Work @default.
- W2976906584 sameAs 2976906584 @default.
- W2976906584 citedByCount "11" @default.
- W2976906584 countsByYear W29769065842020 @default.
- W2976906584 countsByYear W29769065842022 @default.
- W2976906584 countsByYear W29769065842023 @default.
- W2976906584 crossrefType "journal-article" @default.
- W2976906584 hasAuthorship W2976906584A5001723045 @default.
- W2976906584 hasAuthorship W2976906584A5010215345 @default.
- W2976906584 hasAuthorship W2976906584A5040649143 @default.
- W2976906584 hasBestOaLocation W29769065841 @default.
- W2976906584 hasConcept C104304963 @default.
- W2976906584 hasConcept C127413603 @default.
- W2976906584 hasConcept C150394285 @default.
- W2976906584 hasConcept C159985019 @default.
- W2976906584 hasConcept C171250308 @default.
- W2976906584 hasConcept C178790620 @default.
- W2976906584 hasConcept C184651966 @default.
- W2976906584 hasConcept C185592680 @default.
- W2976906584 hasConcept C192562407 @default.
- W2976906584 hasConcept C199289684 @default.
- W2976906584 hasConcept C2777335606 @default.
- W2976906584 hasConcept C2780841128 @default.