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• W2977331353 abstract "Processing of hazardous materials is a crucial example where online monitoring can significantly reduce operation risk, cost, and time. This is particularly true in the case of the Hanford site, where nuclear materials from the Cold War era are being processed for environmental cleanup efforts. In exceedingly complex streams such as those at Hanford, online and real-time monitoring can be challenging due to the complexity of instrument signals. Further obstacles are imposed by the caustic nature of processing streams, as well as the radiation damage inflicted on instruments and probes. Online monitoring based on Raman spectroscopy enables the detection of many Hanford tank species of interest. Nine chemical species that comprise the majority of tank waste by volume, including Al(OH)4–, C2O42–, CO32–, CrO42–, NO3–, NO3–, OH–, PO43–, and SO42–, were detected and quantified. Real-time analysis of Raman signal allows for immediate quantification of target analytes and was successfully accomplished through the..." @default.
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• W2977331353 date "2019-10-06" @default.
• W2977331353 modified "2023-10-10" @default.
• W2977331353 title "Online, Real-Time Analysis of Highly Complex Processing Streams: Quantification of Analytes in Hanford Tank Sample" @default.
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• W2977331353 doi "https://doi.org/10.1021/acs.iecr.9b03636" @default.
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