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- W2977462078 abstract "Aluminum(III) is inherently electron deficient and therefore acts as a prototypical Lewis acid. Conversely, Al(I) is a rare, nucleophilic variant of aluminum that is thermodynamically unstable under ambient conditions. While attempts to stabilize and isolate Al(I) species have become increasingly successful, the parent Al(I) (i.e, Al–H) remains accessible only under extreme temperatures/pressures or matrix conditions. Here, we report the isolation of the parent Al(I) hydride under ambient conditions via the reduction of a Lewis-base-stabilized alkyldihaloalane. Computational and spectroscopic analyses indicate that the ground-state electronic configuration of this monomeric aluminum species is best described as an Al(I) hydride with non-negligible open-shell Al(III) singlet diradical character. These findings are also supported by reactivity studies, which reveal both the p-centered lone pair donating ability and the hydridic nature of the parent aluminene." @default.
- W2977462078 created "2019-10-10" @default.
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- W2977462078 date "2019-10-02" @default.
- W2977462078 modified "2023-10-03" @default.
- W2977462078 title "Lewis-Base Stabilization of the Parent Al(I) Hydride under Ambient Conditions" @default.
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- W2977462078 doi "https://doi.org/10.1021/jacs.9b09128" @default.
- W2977462078 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31577138" @default.
- W2977462078 hasPublicationYear "2019" @default.
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