FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2977893453> ?p ?o ?g. }

• W2977893453 endingPage "31917" @default.
• W2977893453 startingPage "31911" @default.
• W2977893453 abstract "Hydrothermal reactions of the multitopic ligand 1-hydroxy-1-(piperidin-4-yl)methylidenebisphosphonic acid (hpdpH4) with cobalt or nickel sulfates afforded two new isostructural metal phosphonates, M3II(hpdpH)2(H2O)6·4H2O [M = Co (Co-10H2O), Ni (Ni-10H2O)]. Their structures consist of parallel diamond chains of three MO6 octahedra bridged by the PO3C tetrahedra. Six of the seven oxygen atoms of the ligand are involved in coordination; for two ligands that amounts to 12 bonds for 3 MO6 and the remaining six are occupied by terminal water molecules. In addition, four water molecules sit in between the chains providing H-bonds to the formation of a 3D-net. Thermal analyses show identical two-step dehydration processes involving first the departure of six water molecules followed by the remaining four. A detailed study of the ac- and dc-magnetization as a function of temperature, field and frequency reveals associated drastic changes. The virgin form Co-10H2O is a paramagnet while its partial dehydrated form Co-4H2O is an antiferromagnet displaying canting below TN = 4.7 K and the fully dehydrated form Co is a ferrimagnet (TC = 12 K). Ni-10H2O and Ni-4H2O exhibit long-range ordered antiferromagnetism (TN = 2.7 and 4.0 K, respectively) and also become ferrimagnets (TC = 9.4 K) when fully dehydrated to Ni. The dehydrated samples can be fully rehydrated with the complete recovery of both the structures and magnetic properties." @default.
• W2977893453 created "2019-10-10" @default.
• W2977893453 creator A5006635830 @default.
• W2977893453 creator A5010214261 @default.
• W2977893453 creator A5012677331 @default.
• W2977893453 creator A5018278101 @default.
• W2977893453 creator A5022858760 @default.
• W2977893453 creator A5064070361 @default.
• W2977893453 creator A5067986959 @default.
• W2977893453 creator A5081567757 @default.
• W2977893453 date "2019-01-01" @default.
• W2977893453 modified "2023-10-18" @default.
• W2977893453 title "Changes in magnetic order through two consecutive dehydration steps of metal-phosphonate diamond chains" @default.
• W2977893453 cites W1798483944 @default.
• W2977893453 cites W1969360633 @default.
• W2977893453 cites W1976056704 @default.
• W2977893453 cites W1986994230 @default.
• W2977893453 cites W1991088524 @default.
• W2977893453 cites W1996380501 @default.
• W2977893453 cites W1997029240 @default.
• W2977893453 cites W2018462913 @default.
• W2977893453 cites W2022766568 @default.
• W2977893453 cites W2025044983 @default.
• W2977893453 cites W2030223380 @default.
• W2977893453 cites W2045828056 @default.
• W2977893453 cites W2065469091 @default.
• W2977893453 cites W2066342798 @default.
• W2977893453 cites W2070132142 @default.
• W2977893453 cites W2071069468 @default.
• W2977893453 cites W2073475349 @default.
• W2977893453 cites W2074169845 @default.
• W2977893453 cites W2084086466 @default.
• W2977893453 cites W2097863296 @default.
• W2977893453 cites W2115889425 @default.
• W2977893453 cites W2119515755 @default.
• W2977893453 cites W2136642069 @default.
• W2977893453 cites W2140666856 @default.
• W2977893453 cites W2168044423 @default.
• W2977893453 cites W2168204708 @default.
• W2977893453 cites W2168969538 @default.
• W2977893453 cites W2316160781 @default.
• W2977893453 cites W2317501505 @default.
• W2977893453 cites W2326290347 @default.
• W2977893453 cites W2369873627 @default.
• W2977893453 cites W2483791545 @default.
• W2977893453 cites W2536274993 @default.
• W2977893453 cites W2560760591 @default.
• W2977893453 cites W2560769895 @default.
• W2977893453 cites W2583367296 @default.
• W2977893453 cites W2606581244 @default.
• W2977893453 cites W2609746745 @default.
• W2977893453 cites W2613698530 @default.
• W2977893453 cites W2754945136 @default.
• W2977893453 cites W2773546168 @default.
• W2977893453 cites W2778297979 @default.
• W2977893453 cites W2789935770 @default.
• W2977893453 cites W2801376389 @default.
• W2977893453 cites W2804661016 @default.
• W2977893453 cites W2805384946 @default.
• W2977893453 cites W2811035249 @default.
• W2977893453 cites W2886911489 @default.
• W2977893453 cites W2889350309 @default.
• W2977893453 cites W2902227562 @default.
• W2977893453 cites W2917863389 @default.
• W2977893453 cites W2921400421 @default.
• W2977893453 cites W2945409384 @default.
• W2977893453 cites W2946383359 @default.
• W2977893453 cites W2949111218 @default.
• W2977893453 cites W2949353619 @default.
• W2977893453 cites W2962787104 @default.
• W2977893453 cites W4211133177 @default.
• W2977893453 doi "https://doi.org/10.1039/c9ra05722f" @default.
• W2977893453 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35530765" @default.
• W2977893453 hasPublicationYear "2019" @default.
• W2977893453 type Work @default.
• W2977893453 sameAs 2977893453 @default.
• W2977893453 citedByCount "2" @default.
• W2977893453 countsByYear W29778934532021 @default.
• W2977893453 countsByYear W29778934532022 @default.
• W2977893453 crossrefType "journal-article" @default.
• W2977893453 hasAuthorship W2977893453A5006635830 @default.
• W2977893453 hasAuthorship W2977893453A5010214261 @default.
• W2977893453 hasAuthorship W2977893453A5012677331 @default.
• W2977893453 hasAuthorship W2977893453A5018278101 @default.
• W2977893453 hasAuthorship W2977893453A5022858760 @default.
• W2977893453 hasAuthorship W2977893453A5064070361 @default.
• W2977893453 hasAuthorship W2977893453A5067986959 @default.
• W2977893453 hasAuthorship W2977893453A5081567757 @default.
• W2977893453 hasBestOaLocation W29778934531 @default.
• W2977893453 hasConcept C115260700 @default.
• W2977893453 hasConcept C115624301 @default.
• W2977893453 hasConcept C116569031 @default.
• W2977893453 hasConcept C121332964 @default.
• W2977893453 hasConcept C124712363 @default.
• W2977893453 hasConcept C155355069 @default.
• W2977893453 hasConcept C170493617 @default.
• W2977893453 hasConcept C178790620 @default.
• W2977893453 hasConcept C179104552 @default.

• next