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• W2977896643 abstract "The reaction of p-cyano-N,N-dimethylaniline N-oxide, an O-atom donor, with different copper(I) complexes (at room temperature and in acetone) indicates the formation via O-atom transfer of a high-valent copper oxyl species, CuII–O•, a putative key intermediate in the catalytic cycle of copper-containing monooxygenases. The formation of p-cyano-N-hydroxymethyl-N-methylaniline and p-cyano-N-methylaniline as the main products of the reaction highlight the capability of this species to hydroxylate strong C–H bonds (bond dissociation energy ∼ 90 kcal/mol). A plausible mechanism for the reactivity of this catalytic system is proposed." @default.
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• W2977896643 date "2019-10-03" @default.
• W2977896643 modified "2023-09-27" @default.
• W2977896643 title "Dimethylanilinic <i>N</i>-Oxides and Their Oxygen Surrogacy Role in the Formation of a Putative High-Valent Copper–Oxygen Species" @default.
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• W2977896643 doi "https://doi.org/10.1021/acs.inorgchem.9b02066" @default.
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