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- W2977951873 abstract "When bromide-containing waters are disinfected with free chlorine, bromide can be converted into free bromine (principally HOBr). Although often overlooked, chloride and bromide are capable of catalyzing bromination reactions of organic compounds by promoting the formation of BrCl and Br2, respectively. Similarly, HOCl can catalyze bromination reactions by enhancing concentrations of BrOCl. As brominating agents, BrCl, Br2, BrOCl (and the related species Br2O) have been shown to be several orders of magnitude more inherently reactive than HOBr toward several non-ionizable aromatic compounds. Under conditions representative of chlorinated drinking water, BrCl and BrOCl can contribute more than HOBr to overall bromination rates of modestly nucleophilic aromatic compounds. This chapter reviews the literature regarding these reactive brominating agents and discusses their potential influence on bromination rates of disinfection by-product precursors." @default.
- W2977951873 created "2019-10-10" @default.
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- W2977951873 date "2015-01-01" @default.
- W2977951873 modified "2023-09-27" @default.
- W2977951873 title "Catalysis of DBP-Precursor Bromination by Halides and Hypochlorous Acid" @default.
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- W2977951873 doi "https://doi.org/10.1021/bk-2015-1190.ch014" @default.
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