Matches in SemOpenAlex for { <https://semopenalex.org/work/W2978184553> ?p ?o ?g. }
- W2978184553 abstract "Abstract Bismuth has emerged as a promising anode material for sodium‐ion batteries (SIBs), owing to its high capacity and suitable operating potential. However, large volume changes during alloying/dealloying processes lead to poor cycling performance. Herein, bismuth nanoparticle@carbon (Bi@C) composite is prepared via a facile annealing method using a commercial coordination compound precursor of bismuth citrate. The composite has a uniform structure with Bi nanoparticles embedded within a carbon framework. The nanosized structure ensures a fast kinetics and efficient alleviation of stress/strain caused by the volume change, and the resilient and conductive carbon matrix provides an interconnected electron transportation pathway. The Bi@C composite delivers outstanding sodium‐storage performance with an ultralong cycle life of 30 000 cycles at a high current density of 8 A g −1 and an excellent rate capability of 71% capacity retention at an ultrahigh current rate of 60 A g −1 . Even at a high mass loading of 11.5 mg cm −2 , a stable reversible capacity of 280 mA h g −1 can be obtained after 200 cycles. More importantly, full SIBs by pairing with a Na 3 V 2 (PO 4 ) 3 cathode demonstrates superior performance. Combining the facile synthesis and the commercial precursor, the exceptional performance makes the Bi@C composite very promising for practical large‐scale applications." @default.
- W2978184553 created "2019-10-10" @default.
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- W2978184553 date "2019-10-07" @default.
- W2978184553 modified "2023-10-16" @default.
- W2978184553 title "Bismuth Nanoparticle@Carbon Composite Anodes for Ultralong Cycle Life and High‐Rate Sodium‐Ion Batteries" @default.
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- W2978184553 doi "https://doi.org/10.1002/adma.201904771" @default.
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