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- W2978474122 abstract "Molecular mass distribution of isotactic polypropylene was studied under shear deformation on Bridgman anvils at pressures of 2 and 5 GPa. It was established that the values of M w and M n averaged over the entire sample decrease as the shear angle increases. The M n value drops to higher extent with pressure compared to the value of M w . At 2 and 5 GPa, the M w values decrease in a similar manner. At 1 GPa, the M w /M n ratio is virtually independent of the shear angle, whereas at pressures of 2 and 5 GPa, molecular mass distribution becomes wider and, eventually, takes a bimodal character. A two-stage process of mechanical degradation of PP was observed under the studied conditions, and the kinetics of each stage can be described by a first-order equation." @default.
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- W2978474122 date "2001-01-01" @default.
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- W2978474122 title "EFFECT OF HIGH PRESSURE ON MECHANICAL DEGRADATION OF ISOTACTIC POLYPROPYLENE UNDER PLASTIC FLOW" @default.
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