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- W2978591728 abstract "Abstract Complexes of 4-chlorobenzaldehyde thosemicarbazone (H1L) with Ni(II), [Ni(1L)2] 1 and Ag(I), [Ag2(μ-X)2(η1-S-H1L)2(PPh3)2] (X = Cl, 2; Br, 3) have been synthesized and characterized by elemental analysis, IR and 1H NMR spectroscopy. Ag(I) complexes, containing the 4-methylbenzaldehyde thiosemicarbazone (H2L) ligand complexes [Ag2(μ-X)2(η1-S-H2L)2(PPh3)2] (X = Cl, 4; Br, 5) have also been synthesized. Complexes 1, 3 and 4 are also characterized by single crystal crystallography to investigate the effect of substituent at phenyl ring of the thiosemicarbazone on the bonding behavior of these Ag(I) complexes. H1L and its Ni(II) complexes were evaluated for their anti-tubercular activities and it was found that the anti-TB actitivy of H1L was enhanced on complexation with Ni(II) for complex 1. Molecular docking of H1L and its nickel complex has also been examined. The results of these studies support the molecular design of the these molecules and have provided a significant background to further examine their antitubercular activity." @default.
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- W2978591728 date "2020-01-01" @default.
- W2978591728 modified "2023-10-01" @default.
- W2978591728 title "Synthesis and structure of complexes (NiII, AgI) of substituted benzaldehyde thiosemicarbazones and antitubercular activity of NiII complex" @default.
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- W2978591728 doi "https://doi.org/10.1016/j.ica.2019.119187" @default.
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