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• W2978621269 endingPage "103014" @default.
• W2978621269 startingPage "103014" @default.
• W2978621269 abstract "Abstract In this study, an iso-reticular metal-organic framework-3(IRMOF-3) exhibiting microporosity was synthesized from organic linker 2-amino terephthalic acid and salt zinc nitrate hexahydrate (Zn-(NO3)2.6H2O) via catalyst-free, solution-based direct mixing technique. Three samples of IRMOF-3 were post-synthetically functionalized with aminomethyl propanol (AMP) with three different concentrations of 25 wt%, 50 wt% and 75 wt% to produce AMP@IRMOF-3. The structural and texture properties of AMP@IRMOF-3 were studied by FESEM, FTIR, pore size distribution, powder XRD, TGA/DTG, N2 adsorption-desorption isotherms, their selective CO2/CH4 adsorption behaviour over various temperatures (298.15 K, 323.15 K, and 348.15 K). The results showed an enhancement in CO2 adsorption capacity from 1.39 mmol/g to 3.90 mmol/g due to successful incorporation of CO2 philic functionalities. Furthermore, the adsorption isotherms were studied by applying Langmuir, Freundlich, Langmuir-Freundlich, and Toth isotherm models. The isotherms study revealed the unfavourable adsorption behaviour with an increase in AMP loadings with a homogenous system." @default.
• W2978621269 created "2019-10-10" @default.
• W2978621269 creator A5029572482 @default.
• W2978621269 creator A5029913208 @default.
• W2978621269 creator A5045991579 @default.
• W2978621269 creator A5058024240 @default.
• W2978621269 creator A5060705249 @default.
• W2978621269 creator A5068144833 @default.
• W2978621269 creator A5078102681 @default.
• W2978621269 creator A5081134309 @default.
• W2978621269 date "2019-12-01" @default.
• W2978621269 modified "2023-10-16" @default.
• W2978621269 title "Synthesis and characterization of iso-reticular metal-organic Framework-3 (IRMOF-3) for CO2/CH4 adsorption: Impact of post-synthetic aminomethyl propanol (AMP) functionalization" @default.
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