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- W2978631752 endingPage "9299" @default.
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- W2978631752 abstract "A series of unprotected spirocyclic β-prolines and β-homoprolines are prepared by Rh-catalyzed C-H insertion. The key intermediate, a Rh nitrenoid, is generated by the N-O bond cleavage of a substituted isoxazolidin-5-one. The reaction proceeds on a gram scale with a catalyst loading of as little as 0.1 mol %, affording spirocyclic β-amino acids that are otherwise difficult to obtain. The building blocks prepared in this work will likely find applications in medicinal chemistry." @default.
- W2978631752 created "2019-10-10" @default.
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- W2978631752 creator A5028359173 @default.
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- W2978631752 date "2019-10-03" @default.
- W2978631752 modified "2023-10-14" @default.
- W2978631752 title "Synthesis of Unprotected Spirocyclic β-Prolines and β-Homoprolines by Rh-Catalyzed C–H Insertion" @default.
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- W2978631752 doi "https://doi.org/10.1021/acs.orglett.9b03198" @default.
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