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• W2978633017 endingPage "1901912" @default.
• W2978633017 startingPage "1901912" @default.
• W2978633017 abstract "Metal-organic frameworks (MOFs) stand as a promising chemically-active host scaffold for the encapsulation of functional guests, because they could enhance luminescent properties by molecular separation of fluorophores in the nanoscale pores of the MOF crystals. Herein, we show simultaneous nanoconfinement of two fluorophores viz. (A) Fluorescein and (B) Rhodamine B in the sodalite cages of ZIF-8, constructed under ambient conditions through a simple one-pot reaction. We report a novel dual-guest@MOF system, termed: A+B@ZIF-8, which overcomes the intrinsic problem of aggregation caused quenching in the solid-state to gain bright yellow emission under UV irradiation. Subsequently, we combine this yellow emitter with a blue-emitting photopolymer resin, to yield a 3D printable luminescent composite material. We design a number of 3D printable composite objects for converting UV into warm white light emission, achieving a high quantum yield of ~44% in the solid-state 3D printed form. This research instigates the bespoke application of a vast range of 3D printable Guest@MOF designer composites targeting energy-saving lighting devices, smart sensors and future optoelectronics." @default.
• W2978633017 created "2019-10-10" @default.
• W2978633017 creator A5031466468 @default.
• W2978633017 creator A5073692835 @default.
• W2978633017 date "2020-02-17" @default.
• W2978633017 modified "2023-09-24" @default.
• W2978633017 title "Dual‐Guest Functionalized Zeolitic Imidazolate Framework‐8 for 3D Printing White Light‐Emitting Composites" @default.
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• W2978633017 doi "https://doi.org/10.1002/adom.201901912" @default.
• W2978633017 hasPublicationYear "2020" @default.
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