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- W2978955951 abstract "Chemical doping is an indispensable tool to tailor the properties of the commercial piezoelectric materials. However, a high piezoelectric coefficient with enhanced thermal stability is rarely achieved by one dopant in some high-performance ferroelectrics, e.g., the recently discovered eco-friendly (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 (BCZT) ceramics. In order to optimize the piezoelectric property in BCZT system by a simple way, we investigated the doping effect of Fe3+, Nb5+ and Bi3+ cations in BCZT ceramics respectively. The results indicate that only Nb5+-doped BCZT ceramics display a combination of large piezoelectric coefficient and enhanced thermal stability, compared with others. Moreover, the established phase diagrams and in-situ transmission electron microscope (TEM) observations reveal that such optimized piezoelectric properties after Nb5+ doping originates from (i) the low polarization anisotropy near the ambient tetragonal (T)-orthorhombic (O) phase transition and (ii) the easy domain wall motion of persistent miniaturized ferroelectric domains upon heating." @default.
- W2978955951 created "2019-10-10" @default.
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- W2978955951 date "2020-02-01" @default.
- W2978955951 modified "2023-10-16" @default.
- W2978955951 title "Large piezoelectric coefficient with enhanced thermal stability in Nb5+-doped Ba0.85Ca0.15Zr0.1Ti0.9O3 ceramics" @default.
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- W2978955951 doi "https://doi.org/10.1016/j.ceramint.2019.10.028" @default.
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