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- W2978999879 abstract "A catalyst system consisting of RuHCl(CO)(PiPr3)2, CsF, and a styrene derivative was found to be applicable to selective monoarylation of aromatic ketones via ortho C–H bond cleavage. The reaction of 2′-methoxyacetophenone with arylboronates gave C–H arylation products without cleaving the ortho C–O bond. Acetophenone was also converted to monoarylation products with high selectivity. Cyclohexanone was found to be an effective solvent for the C–H arylation using the catalyst system." @default.
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- W2978999879 date "2019-09-19" @default.
- W2978999879 modified "2023-10-14" @default.
- W2978999879 title "Selective Monoarylation of Aromatic Ketones via C–H Bond Cleavage by Trialkylphosphine Ruthenium Catalysts" @default.
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- W2978999879 doi "https://doi.org/10.1021/acs.joc.9b01756" @default.
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